What is the basic difference between the terms electron gain enthalpy and electronegativity?
The first and the second ionization enthalpies (in kJ mol-1) and the electron gain enthalpy (in kJ mol-1) of a few elements are given below:
Elements
I 520 7300 -60
II 419 3051 -48
III 1681 3374 -328
IV 1008 1846 -295
V 2372 5251 +48
VI 738 1451 -40
Which of the above elements is likely to be:
(a) the least reactive element.
(b) the most reactive metal.
(c) the most reactive non-metal.
(d) the least reactive non-metal.
(e) the metal which can form a stable binary halide of the formula MX2(X =halogen).
(f) the metal which can form a predominantly stable covalent halide of the formula MX(X= halogen)?
The plot of square root of frequency of X-ray emitted against atomic number led to suggestion of which law/rule?
Periodic law
Modern periodic law
Hund's rule
Newland's law
B.
Modern periodic law
Moseley, gave modern periodic law. He showed that atomic number is more fundamental property of an element than its atomic mass as follows.
"The square root of the frequency of a line (of X-ray spectrum) is related to the atomic number Z of the target material as,
√V = a (Z- b)
where, a= proportionality constant
Z = atomic number
b = another constant
L it has the same value for all the lines of X-rays spectrum.
Which of the following represents the correct order of increasing first ionisation enthalpy for Ca, Ba, S, Se and Ar?
Ca <S<Ba<Se<Ar
S< Se<Ca<Ba< Ar
Ba< Ca<Se< S< Ar
Ba< Ca<Se< S< Ar
The first ionisation potential of Na is 5.1 eV. The value of electron gain enthalpy of Na+ will be
-2.55 eV
-5.1 eV
-10.2 eV
-10.2 eV
The increasing order of the ionic radii of the given isoelectronic species is
Cl-, Ca2+, K+, S2-
S2-, Cl-, Ca2+,K+
Ca2+, K+, Cl-, S2-
Ca2+, K+, Cl-, S2-
The outer electron configuration of Gd (Atomic No : 64) is
4f3 5d5 6s2
4f8 5d0 6s2
4f4 5d4 6s2
4f4 5d4 6s2
The correct sequence which shows decreasing order of the ionic radii of the elements is
Al3+ > Mg2+ > Na+ > F- > O2-
Na+ > Mg2+ > Al3+ > O2- > F-
Na+ > F- > Mg2+ > O2- > Al3+
Na+ > F- > Mg2+ > O2- > Al3+
The set representing the correct order of ionic radius is
Li+> Be2+> Na+> Mg2+
Na+>Li+>Mg2+> Be2+
Li+>Na+ > Mg2+ > Be2+
Li+>Na+ > Mg2+ > Be2+