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 Multiple Choice QuestionsLong Answer Type

181.

What is the basic difference between the terms electron gain enthalpy and electronegativity?

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182.

The first left parenthesis increment subscript straight i straight H subscript 1 right parenthesis and the second left parenthesis increment subscript straight i straight H subscript 2 right parenthesis ionization enthalpies (in  kJ mol-1) and the left parenthesis increment subscript eg straight H right parenthesis electron gain enthalpy (in kJ mol-1) of a few elements are given below:
Elements            increment straight H subscript 1               increment straight H subscript 2                 increment subscript eg straight H
I                        520                    7300                    -60
II                       419                     3051                   -48
III                      1681                    3374                  -328
IV                       1008                    1846                 -295
V                         2372                    5251                 +48
VI                        738                      1451                -40  
Which of the above elements is likely to be:
(a) the least reactive element.
(b) the most reactive metal.
(c) the most reactive non-metal.
(d) the least reactive non-metal.
(e) the metal which can form a stable binary halide of the formula MX2(X =halogen).
(f) the metal which can form a predominantly stable covalent halide of the formula MX(X= halogen)?

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 Multiple Choice QuestionsMultiple Choice Questions

183.

The plot of square root of frequency of X-ray emitted against atomic number led to suggestion of which law/rule?

  • Periodic law

  • Modern periodic law

  • Hund's rule

  • Newland's law


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184.

Which of the following atoms has the highest first ionisation energy?

  • Na

  • K

  • Sc

  • Sc


C.

Sc

Order of first ionisation energy is Sc> Na > K > Rb. Due to poor shielding effect, removal of one electron from 4s orbital is difficult as compared to 3s-orbital.

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185.

Which of the following represents the correct order of increasing first ionisation enthalpy for Ca, Ba, S, Se and Ar?

  • Ca <S<Ba<Se<Ar

  • S< Se<Ca<Ba< Ar

  • Ba< Ca<Se< S< Ar

  • Ba< Ca<Se< S< Ar

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186.

The first ionisation potential of Na is 5.1 eV. The value of electron gain enthalpy of Na+ will be

  • -2.55 eV

  • -5.1 eV

  • -10.2 eV

  • -10.2 eV

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187.

The increasing order of the ionic radii of the given isoelectronic species is 

  • Cl-, Ca2+, K+, S2-

  • S2-, Cl-, Ca2+,K+

  • Ca2+, K+, Cl-, S2-

  • Ca2+, K+, Cl-, S2-

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188.

The outer electron configuration of Gd (Atomic No : 64) is

  • 4f3 5d5 6s2

  • 4f8 5d0 6s2

  • 4f4 5d4 6s2

  • 4f4 5d4 6s2

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189.

The correct sequence which shows decreasing order of the ionic radii of the elements is

  • Al3+ > Mg2+ > Na+ > F- > O2-

  • Na+ > Mg2+ > Al3+ > O2- > F-

  • Na+ > F- > Mg2+ > O2- > Al3+

  • Na+ > F- > Mg2+ > O2- > Al3+

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190.

The set representing the correct order of ionic radius is

  • Li+> Be2+> Na+> Mg2+

  • Na+>Li+>Mg2+> Be2+

  • Li+>Na+ > Mg2+ > Be2+

  • Li+>Na+ > Mg2+ > Be2+

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