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 Multiple Choice QuestionsMultiple Choice Questions

371.

The ions N3-, O2-, F-, Na+, Mg2+ are isoelectronic. Their ionic radii show

  • an increase from N3- to F- and then decrease from N+ to Mg2+

  • a decrease from N3- to F- and then increase from Na+ to Mg2+

  • a significant increase from N3- to Mg2+

  • a significant decrease from N3- to Mg2+


372.

Which of the following pairs of ions cannot be separated by H2S in dilute HCl?

  • Bi3+, Sn4+

  • Al3+, Hg2+

  • Cu2+, Zn2+

  • Ni2+, Cu2+


373.

The radius of H-atom in its ground state is 0.58Å .The radius of, 3Li2+ ithe similar state is

  • 0.1777 Å

  • 0.706 Å

  • 1.06 Å

  • 0.058 Å


374.

The correct order of ionization energies is

  • Cu > Ag > Au

  • Cu > Au > Ag

  • Au > Cu > Ag

  • Ag > Au > Cu


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375.

The set representing the correct order of ionic radius is

  • Li+ > Be2+ > Na+ > Mg2+

  • Na+ > Li+ > Mg2+ > Be2+

  • Li+ > Na+ > Mg2+ > Be2+

  • Mg2+ > Be2+ > Li+ > Na+


376.

Which of the following is the correct decreasing order of oxidation state of nitrogen?

  • HNO3 > NO > NH4Cl > N2

  • HNO3 > NO > N2 > NH4Cl

  • HNO3 > NH4Cl > NO > N2

  • NO > HNO3 > NH4Cl > N2


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377.

Which of the following has highest electron affinity?

  • N

  • O

  • F

  • Cl


D.

Cl

The electron affinities of some of the elements of second period ( i.e. N, O, F, etc) are however, lower than the corresponding elements ( i.e P, S, Cl, etc) of the third period. This is due to the reason that the elements of second period have the smallest atomic sizes amongst  the elements in their respective groups. As a result, there are considerable electron-electron repulsion with the atom itself and hence, the additional electron is not accepted with the same case as compared to the remaining elements in the same group.


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378.

The one electron species having ionisation energy of 54.4 eV is

  • He+

  • H

  • Be2+

  • Be3+


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379.

Ionisation energy in group 1A varies in the decreasing order as

  • Li > Na > K > Cs

  • Na > Li > K > Cs

  • Li > Cs > K  Na

  • K > Cs > Na > Li


380.

An example of a non-stoichiometric compound is

  • PbO

  • NiO2

  • Al2O3

  • Fe3O4


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