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 Multiple Choice QuestionsMultiple Choice Questions

401.

Which one of the following ion has electronic configuration [Ar] 3d6?
(At. no:  Mn = 25, Fe = 26, Co = 27, Ni = 28)

  • Ni3+

  • Mn

  • Fe3+

  • Fe3+

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402.

Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is 

  • Mg< Ca < Cl < P

  • Cl < P < Mg < Ca

  • P < Cl < Ca < Mg

  • P < Cl < Ca < Mg

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403.

Among the following which one has the highest cation to anion size ratio?

  • CsI

  • CsF

  • LiF

  • LiF

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404.

Which one of the element with the following outer orbital configuration may exhibit the largest number of oxidation states?

  • 3d5,4s2

  • 3d5,4s1

  • 3d5,4s2

  • 3d5,4s2

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405.

Oxidation number of P in PO43-, of S in SO42- and that of Cr in Cr2O72- are respectively,

  • +5,+6 and +6

  • +3, + 6 and +5

  • +5,+3 and +6

  • +5,+3 and +6

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406.

Amongst the elements with following electronic configuration, which one of them may have the highest ionisation energy?

  • [Ne] 3s2 3p3

  • [Ne] 3s2 3p2

  • [Ar] 3d10, 4s2 4p3

  • [Ar] 3d10, 4s2 4p3

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407.

The correct order of decreasing second ionisation enthalpy of Ti (22), V (23), Cr(24) and Mn (25) is 

  • Cr > Mn> V > Ti

  • V > Mn > Cr >Ti

  • Mn > Cr> Ti >V

  • Mn > Cr> Ti >V


A.

Cr > Mn> V > Ti

The amount of energy required to remove an electron from unipositive ions is called the second IP which generally increases in a period from left to right.
The second ionisation energies of the first transition series increase almost regularly with an increase in atomic number. However, the value for Cr is sufficiently higher than those of its neighbour ie, (Mn). This is due to the stable configuration of Cr3+ (3d5 exactly half filled.)


[Note: The half-filled and completely filled configuration are more stable.]

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408.

The sequence of ionic mobility in aqueous solution is 

  • K+ > Na+ > Rb+ > Cs+

  • Cs+ > Rb+ > K+ >Na+

  • Rb+ > K+> Cs+ > Na+

  • Rb+ > K+> Cs+ > Na+

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409.

Which of the following oxidation states are the most characteristics for lead and tin respectively? 

  • +4,+2

  • +2,+4

  • +4,+4

  • +4,+4


410.

Consider the following sets of quantum numbers:


  n l m s
i) 3 0 0 +1/2
ii) 2 2 1 +1/2
iii) 4 3 -2 -1/2
iv) 1 0 -1 -1/2
v) 3 2 3 +1/2

Which of the following sets of quantum number is not possible? 
  • ii, iii and iv

  • i, ii, iii and iv

  • ii, iv and v

  • ii, iv and v


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