Important Questions of Coordination Compounds Chemistry | Zigya

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 Multiple Choice QuestionsShort Answer Type

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211.

Explain the following:
[Ni(H2,O)6]2+ turns blue when changed to [Ni(NH3)6]3+ by adding NH3

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212.

Explain the following:
Violet coloured [Cr(H2O)6]3+ becomes bright blue when reduced to [Cr(H2O)6]2+

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 Multiple Choice QuestionsLong Answer Type

213. What do you understand by the term stability constant, K of a complex? Knowing that the value of K for [Cu(NH3)4]2+ is 4.5 x 1011 and for [Cu(CN)4]2– is 2.0 x 1027, suggest
(a) Which complex species will furnish less Cu2+ ions in solution and 
(b) Which out of NH3and CN is a stronger ligand?
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 Multiple Choice QuestionsShort Answer Type

214. Illustrate with an example ionization isomerism in coordination compounds.
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215. Formation of complex is exothermic or endothermic process. Explain why? What is the effect of temperature on stability of complex compound?
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216. Give the IUPAC name of [CrCl2 (H2O)4]Cl
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217.

Give the number of unpaired electrons in the following complex ions:
[FeF6]4– and [Fe(CN)6]4–

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218.

Name the isomerism exhibited by the following pair of coordination compounds:
[Co(NH3)5Br]SO4 and [Co(NH3)5SO4] Br

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219. What is a ligand? Give an example of a bidentate ligand.
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 Multiple Choice QuestionsLong Answer Type

220.

Explain as to how the two complexes of nickel, [Ni(CN)4]2– and Ni(CO)4, have different structures but do not differ in their magnetic behaviour (Ni = 28).

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