Indicate the type of isomerism exhibited by the following complex
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    Coordination Compounds

    Multiple Choice QuestionsShort Answer Type

    1. Write the formula for the following coordination compound:
    Tetraaminediaquacobalt(lll)chloride
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    2. Write the formula for the following coordination compound:
    Potassium tetracyanidonickelate(II)
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    3. Write the formula for the following coordination compound:
    Tris(ethane -1, 2-diamine) chromium(III) chloride
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    4. Write the formula for the following coordination compound:
    Amminebromidochloridonitrito-N-platinate (II)
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    5. Write the formula for the following coordination compound:
    Dichloridobis(ethane-1, 2-diamine)platinum(lV) nitrate.
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    6. Write the formula for the following coordination compound:
    Iron(III) hexacyanidoferrate(II)
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    7. Write the IUPAC names of the following coordination compounds:
    (i) [Co(NH3)6]Cl3
    (ii) [Co(NH3)5Cl]Cl2
    (iii) K    3[Fe(CN)6]
    (iv) K    3[Fe(C2O4)3]
    (v) K    2[PdCl4]
    (vi) [Pt(NH    3)2Cl(NH2CH3)]Cl.
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    8.

    Indicate the type of isomerism exhibited by the following complexes and draw structures for these isomers:
    (i)    K[Cr(H2O)2(C2O4)2],                      (ii) [Co(en)3Cl3,
    (iii) [Co(NH3)5(NO2)]|NO3]2,                 (iv) [Pt(NH3)(H2O)Cl2]

    (i) Both geometrical (Cis, trans) and optical isomers for Cis can exist.

    (ii) Two optical isomers can exist.

    (iii) There are 10 possible isomers. There are geometrical, ionisation and linkage isomers possible.

    (iv) Geometrical (Cis, trans) isomers can exist.

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    9.

    Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionisation isomers.

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    Multiple Choice QuestionsLong Answer Type

    10. Explain on the basis of valence bond theory that [Ni(CN)4]2–  ion with square planar is diamagnetic and the [NiCl4]2– ion with tetrahedral geometry is paramagnetic.
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