Write the IUPAC name of [Ni(CN)4]2– ion? from Che

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 Multiple Choice QuestionsShort Answer Type

71. What is Wilkinson’s catalyst? Where is it used?
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72.

Write the IUPAC name of [Ni(CN)4]2– ion?


Tetracyano nickelate (II) ion.
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73. Nickel carbonyl( NiCO4) has tetrahedral geometry whereas [Pt(NH3)2Cl2] is square planar.
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74.

Write the expression for the stability’ constant for [Cu(NH3)4]2+.

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75.

The value of equilibrium constants of [Cu(NH3)4]+ and [Co(NH3)6]3+ are 1.0 x 10–12 and 6.2 x 10–36 respectively. Which complex would be more stable and why ?

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76.

In octahedral complexes which two d-orbitals are used in hybridization.

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77.

If the value of Δ0 is less than P in the crystal field, write the arrangement of d4coordination entity in crystal field split.

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78.

How is ammonia molecule  is a good ligand?

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79.

What do you understand by the term stability constant K for a complex?

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80. There are two compounds [Cr(NH3)4]2+ and [Cr(CN)4]2– having 5.2 x 1011 and 3.2 x 1022 respectively as their K values, which complex is more stable and which ligand NH3or CN is a stronger ligand?
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