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 Multiple Choice QuestionsShort Answer Type

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101.

Write the formula of the first f-block organometallic synthesised.


F-block metallocenes is tris(cyclopentadienyl) lanthanide complexes, (C5H5)3Ln (Ln = La, Ce, Pr, Nd, Sm and Gd).

Where C
5Me = Pentamethyl cyclopentadieny.
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102.

What is the oxidation state of the metal in the following coordiantion compound?
(i) Ni in Ni(CO)4    (ii) Co in [Co(CO) 4]

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103.

Which part of the d-block metals forms stable metal carbonyls?

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104.

If the geometry of [PtCl4]2– is square planar, which orbitals of Pt are involved in the bonding?

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105.

What is the charge on the complex of Pt2+ in which the ligands are - one water molecule, one pyridine molecule and one ethylene diamine molecule?

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106.

Name the type of isomerism that occurs in complexes in which both cation and anion are complex ions.

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107. Write down the IUPAC names of the following compounds:
(i) [Co(NH3)5ONO]Cl2,    (ii) K3[Cr(CN)6]        
(iii) [Cr(NH3)5CO3]Cl
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108.

Write formula of the following complexes:
(i) Penta amine chlorocobalt(II)
(ii) Lithium tetrahydro aluminate(III).

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109.

Which of the following will give white precipitate with AgNO3 solution:
[Pt(NH3)2Cl4],   K[Pt(NH3)Cl5],    [Pt(NH3)3 Cl3]Cl?

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110.

How many moles of ions are formed when one mole of the complex, [Co(NH3)4Cl2]Cl is completely dissociated into ions?

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