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 Multiple Choice QuestionsLong Answer Type

191.

What is meant by stability of coordinate compound in solution? State the factors which govern stability of complexes.

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 Multiple Choice QuestionsShort Answer Type

192. What is meant by the chelate effect? Give an example.  
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193. Discuss briefly the role of coordination compounds in biological systems.


Biological system:

(i) Haemoglobin the red blood cell which acts as oxygen carrier to different parts of the body is a complex of iron(II).

(ii) Vitamin B12 is a complex of cobalt metal. Trace metals also function through coordination processes.

(iii) A complex of zinc(II) called enzyme CPA helps in digestion of food.

(iv) The chlorophyll, the green colouring plant pigment that plays an important role in photosynthesis is a complex of magnesium. In chlorophyll Mg is coordinated to four nitrogens of porphyin units.

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194. Discuss briefly the role of coordination compounds in analytical chemistry.
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195. Discuss briefly the role of coordination compounds in medicinal chemistry.
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196. Discuss briefly the role of coordination compounds in extraction/metallurgy of metals.
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197.

What is macrocyclic effect?

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198.

How does the metal carbonyls gain stability although CO is a weak donor?

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199.  [CoF6]3– is paramagnetic whereas [Co(C2O4)3]3– is diamagnetic. Why?
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200. [NiCl4]2– is paramagnetic in nature, explain.
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