How does the metal carbonyls gain stability although CO is a weak

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 Multiple Choice QuestionsLong Answer Type

191.

What is meant by stability of coordinate compound in solution? State the factors which govern stability of complexes.

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 Multiple Choice QuestionsShort Answer Type

192. What is meant by the chelate effect? Give an example.  
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194. Discuss briefly the role of coordination compounds in analytical chemistry.
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196. Discuss briefly the role of coordination compounds in extraction/metallurgy of metals.
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197.

What is macrocyclic effect?

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198.

How does the metal carbonyls gain stability although CO is a weak donor?


The metal -carbon bond in metal carbonyls posses both σ and π character. The M–C σ bond is formed by the donation of lone pair of electrons on the metal. The M–C π bond is formed by the donation of a pair of electrons from a filled d orbital of metal into the vacant antibonding π* orbital of carbon monoxide. The metal to ligand bonding creates a synergic effect which strengthens the bond between CO and the metal.

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199.  [CoF6]3– is paramagnetic whereas [Co(C2O4)3]3– is diamagnetic. Why?
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