[NiCl4]2– has ________  geometry and Ni(CO)

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 Multiple Choice QuestionsShort Answer Type

221. What is the basis of formation of the spectrochemical series?
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 Multiple Choice QuestionsLong Answer Type

222.

Draw the structures of geometrical isomers of the following coordination complexes:
[Co(NH3)3Cl3] and [CoCl2(en)2+]
(en = ethylene diamine and atomic number of Co is 27).   

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223. Explain with examples geometric and optical isomerism.
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 Multiple Choice QuestionsShort Answer Type

224. Mention the geometrical shapes attained by the following types of hybrid orbitals: (a) sp3, (b) dsp2, (c) d2sp3. Give an example for each.
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 Multiple Choice QuestionsLong Answer Type

225. Illustrate the isomerism:
Coordination isomerism in coordination compounds.
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 Multiple Choice QuestionsShort Answer Type

226. A metal ion Mn+ having d4 valence electronic configuration combines with three didendate ligands to form complex compound. Assuming ∧0 > P.

(i)  Draw the diagram showing d-orbital splitting during this complex formation.
(ii) Write the electronic configuration of the valence electrons of the metal Mn+ in terms to t2g, and eg .

(iii) What type of hybridisation will Mn+ ion have?

(iv) Name the type of isomerism exhibited by this complex.
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227.

Illustrate with an example of the following:
Linkage isomerism

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 Multiple Choice QuestionsLong Answer Type

228.

(i) Explain geometrical isomerism with reference to square planar complexes giving one example. How is tetrahedral complexes with simple ligands do not exhibit geometrical isomerism?
(ii)    Using valence bond theory, predict the shape and magnetism (paramagnetism) or diamagnetism of [Co(CO)4] (at. no. of Co = 27)?
(iii)    How is stability of coordination compounds determined in aqueous solution?

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 Multiple Choice QuestionsFill In the Blanks

229. In [Co(C2O4)3]3–, the coordination number of cobalt is ________.
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230.  [NiCl4]2– has ________  geometry and Ni(CO)4 has _______ geometry.


tetrahedral

,

tetrahedral

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