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 Multiple Choice QuestionsShort Answer Type

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271.

What is coordination number of metal ion in [Pt(NH3)2(C2O4)]?


In this complex the coordination number of metal ion is 4. such to two electron pair from diamine and 2 electron pair from oxalate (didentate ligand).

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272. How would you account for the fact that both Ni(CO)4 and (NiCl4)2– have a tetrahedral geometry? (Atomic number of Ni = 28). Which one has a higher magnetic moment?
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273.

What do you understand by crystal field splitting? Draw figure to show splitting of degenerate d-orbitals in an octahedral crystal field.

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274.

What are the main postulates of Werner’s theory? Write the correct formula and IUPAC name of the coordination compound for CrCl3.6H2O, one mole of which give two moles of AgCl with AgNO3,.

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275. [Ni(CO)4 has a tetrahedral geometry whereas [Ni(CN)4]4– has square planar geometry. Why?
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276. [Fe(CN)6]4– is diamagnetic while [FeF6]4– is strongly paramagnetic. Why?
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277.

What is complex? How is it different from a double salt?

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 Multiple Choice QuestionsLong Answer Type

278.

Give the systematic name for each of the following compounds:

(i)[Pt(NH3)4Cl2][PtCl4]         
(ii) [Cr(CO)5Cl](ClO3)2     
(iii) K3[Cr(CN)6]
(iv)[Co(NH)4Cl2]+ 
(v) (NH4)3[Co(NO2)6]            
(vi) K2[CuCl4]

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279.

Give the chemical formula for each of the following compounds:
(i) Potassium hexanitro cobaltate(III).
(ii) Potassium hexacyano cobaltate(III).
(iii) Ammonium trans-dichlorodiodo aurate(III).
(iv) Sodium pentacyano carbonyl ferrate(II).
(v) Diamminechlorido(methylamine)plantinum(II)
chloride.
(vi)Dichloridobis(ethane–1,2diamine)platinum(IV) nitrate

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 Multiple Choice QuestionsShort Answer Type

280. Explain the geometry of [Cr(NH3)6]3+ ion by valence bond theory of complexes. Why is this not diamagnetic?
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