The number of unpaired electrons in[NiCl4]2-, Ni(CO)4 and (Cu(NH3

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 Multiple Choice QuestionsShort Answer Type

321.

Write the IUPAC name of the following complex : [Co(NH3)5(CO3)]Cl.

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322.

Write the coordination number and oxidation state of Platinum in the complex [Pt(en)2Cl2].


323.

Write the formula of the following coordination compound :
Iron(III) hexacyanoferrate (II)


324.

What type of isomerism is exhibited by the complex [Co(NH3)5 Cl]SO4?


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325.

Write the hybridisation and number of unpaired electrons in the complex [CoF6]3-.

Atomic No. of Co = 27


326.

Identify the chiral molecule in the following pair :


327.

Sc3+ is colourless in aqueous solution whereas Ti3+ is coloured.


328.

Give reason:

When Cl2 reacts with an excess of F2. ClF3 is formed and not FCl3


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 Multiple Choice QuestionsMultiple Choice Questions

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329.

The number of unpaired electrons in[NiCl4]2-, Ni(CO)4 and (Cu(NH3)4]2+ respectively are

  • 0, 2, 1

  • 2, 0, 1

  • 0, 2, 1

  • 2, 2, 0


B.

2, 0, 1

Configuration for metal (M) in various complex.

Ni2+ has 2 unpaired electrons.

Ni0 has zero unpaired electrons with sp3-hybridisation.

Cu2+ has one unpaired electron with dsp2-hybridisation.

Therefore, number of unpaired electrons is (2, 0, 1).


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330.

The pair having the same magnetic moment is:

[At. No. : Cr=24, Mn=25, Fe=26, Co=27]

  • [Cr(H2O)6 ]2+ and [Fe(H2O)6 ]2+

  • [Mn(H2O)6 ]2+ and [Cr(H2O)6 ]2+

  • [CoCl4 ]2− and [Fe(H2O)6 ]2+

  • [CoCl4 ]2− and [Fe(H2O)6 ]2+

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