The number of stereoisomers possible for a compound of the molecular formula CH3-CH =CH-(OH)-Me is
3
2
4
4
Which of the following pairs represents linkage isomers?
[Cu(NH3)4][PtCl4] and [Pt(NH3)4][CuCl4]
[Pd(PPh3)2(NCS)2] and [Pd(PPh3)2(SCN)2]
[CO(NH3)5NO3]SO4 and [CO(NH3)5SO4]NO3
[CO(NH3)5NO3]SO4 and [CO(NH3)5SO4]NO3
The coordination number and the oxidation state of the element ‘E’ in the complex [E(en)2(C2O4)]NO2 (where(en) is ethylene diamine) are, respectively,
6 and 2
4 and 2
4 and 3
4 and 3
In which of the following octahedral complexes of Co (at. no. 27), will the magnitude of ∆o be the highest?
[Co(CN)6]3−
[Co(C2O4)3]3−
[Co(H2O)6]3+
[Co(H2O)6]3+
Which one of the following has a square planar geometry?
[CoCl4]2-
[FeCl4]2–
[NiCl4] 2–
[NiCl4] 2–
Which of the following molecules is expected to rotate the plane of plane-polarised light?
In which of the following ionization processes, the bond order has increased and the magnetic behaviour has changed?
C2 → C2+
NO → NO+
O2 → O2+
O2 → O2+
B.
NO → NO+
D.
O2 → O2+
C2 → C2+ electron is removed from bonding molecular orbital so bond order decreases. In NO → NO+, electron is removed from antibonding molecular orbital so bond order increases and nature changes from paramagnetic to diamagnetic.
Which one of the following conformation of cyclohexane is chiral?
Twist boat
Rigid
chair
chair