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 Multiple Choice QuestionsMultiple Choice Questions

361.

The IUPAC name for the complex [Co(NO2)(NH3)5]Cl2 is

  • nitrito-N-pentaamminecobalt (III) chloride

  • nitrito-N-pentaamminecobalt (II) chloride

  • pentaammine nitrito-N-cobalt (II) chloride

  • pentaammine nitrito-N-cobalt (II) chloride

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362.

Increasing order of stability among the three main conformations (i.e. Eclipse, Anti, Gauche) of 2-fluoroethanol is

  • Eclipse, Gauche, Anti

  • Gauche, Eclipse, Anti

  • Eclipse, Anti, Gauche

  • Eclipse, Anti, Gauche

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363.

How many EDTA (ethylenediaminetetraacetic acid) molecules are required to make an octahedral complex with a Ca2+ ion?

  • 6

  • 3

  • 1

  • 1

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364.

The oxidation state of Cr in [Cr(NH3)4Cl2]+ is

  • +3

  • +1

  • 0

  • 0

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365.

The IUPAC name of the coordination compound K3[Fe(CN)6] is

  • Potassium hexacyanoferrate (II)

  • Potassium hexacyanoferrate (III)

  • Potassium hexacyanoiron (II)

  • Potassium hexacyanoiron (II)

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366.

Which of the following compounds shows optical isomerism?

  • [Cu(NH3)4]+2

  • [ZnCl4]-2

  • [Cr(C2O4)3]-3

  • [Cr(C2O4)3]-3

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367.

Which one of the following cyano complexes would exhibit the lowest value of paramagnetic behaviour?

  • [Cr(CN)6]-3

  • [Mn(CN)6]-3

  • [Fe(CN)6]-3

  • [Fe(CN)6]-3

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368.

Which types of isomerism is shown by 2,3-dichlorobutane?

  • Diastereo

  • Optical

  • Geometric

  • Geometric

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369.

The value of the ‘spin only’ magnetic moment for one of the following configurations is 2.84 BM. The correct one is

  • d4 (in strong ligand filed)

  • d4 (in weak ligand field)

  • d3 (in weak as well as in strong fields)

  • d3 (in weak as well as in strong fields)


A.

d4 (in strong ligand filed)



d4 in strong field, so unpaired electrons = 2
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370.

For which of the following parameters the structural isomers C2H5OH and CH3OCH3 would be expected to have the same values?

  • Heat of vaporization

  • Gaseous densities at the same temperature and pressure

  • Boiling points

  • Boiling points

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