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 Multiple Choice QuestionsMultiple Choice Questions

461.

IUPAC name of Na3[Co(NO2)6] is

  • sodium hexanitrito cobaltate (II)

  • sodium hexanitro cobaltate (III)

  • sodium hexanitrito cobaltate (III)

  • sodium cobaltnitrite


462.

A complex compound in which the oxidation number of a metal is zero is

  • K4[Fe(CN)6]

  • K3[Fe(CN)6]

  • [Ni(CO)4]

  • [Pt(NH3)4]Cl2


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463.

Which complex cannot ionise in solution?

  • [CoCl3(NH3)3]

  • K4[Fe(CN)6]

  • K2[Pt(F6)]

  • [Pt(NH3)6]Cl4


A.

[CoCl3(NH3)3]

[CoCl3(NH3)3] cannot ionise in solution because three chloride ions satisfy primary and secondary valencies. It will not be precipitated by the addition of AgNO3.


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464.

The IUPAC name of [Co(NH3)5ONO]2+ ion is

  • penta ammine nitrito cobalt (IV) ion

  • penta ammine nitrito cobalt (III) ion

  • penta ammine nitro cobalt (III) ion

  • penta ammine nitro cobalt (IV) ion


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465.

The IUPAC name of K2[Ni(CN)4] is

  • potassium tetracyanonickelate (II)

  • potassium tetracyanatonickelate (III)

  • potassium tetracyanatonickel (II)

  • potassium tetracyanonickel (III)


466.

The IUPAC name of the complex [Co(NH3)4Cl2]Cl is

  • dichloro tetraammine cobalt (III) chloride

  • tetraammine dichloro cobalt (III) chloride

  • tetraammine dichloro cobalt (II) chloride

  • tetraammine dichloro cobalt (IV) chloride


467.

Which one of the following is wrongly matched?

  • [Cu(NH3)4]2+  - Square planar

  • [Ni(CO)4]   - Netural ligand

  • [Fe(CN6)3-]  -  sp3d2

  • [Co(en)3]3+    - Follows EAN


468.

The atomic number of cobalt is 27. The EAN of cobalt in Na3[CoNO2)4Cl2] is

  • 24

  • 36

  • 34

  • 35


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469.

The secondary valency of platinum in tetra amminedichloroplatinum (IV) chloride is

  • +2

  • 3

  • 6

  • +4


470.

In which one of the pairs of ion given, there is an ion that forms a coordination compound with both aqueous sodium hydroxide and ammonia and an other ion that forms a coordination compound only with aqueous sodium hydroxide?

  • Pb2+, Cu2+

  • Zn2+, Al3+

  • Cu2+, Zn2+

  • Al3+, Cu2+


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