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 Multiple Choice QuestionsMultiple Choice Questions

481.

Copper sulphate solution, when added to an excess of ammonium hydroxide, forms a complex compound due to :

  • [Cu(NH3)2]2+

  • [Cu(NH3)4]2+

  • [Cu(NH3)6]2+

  • Cu2+


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482.

Mohr salt is made up of which combination of salt?

  • Ammonium sulphate and potash

  • Ammonium sulphate and ferrous sulphate

  • Ammonium sulphate and copper sulphate

  • Ammonium sulphate and magnesium sulphate


B.

Ammonium sulphate and ferrous sulphate

Mohr salt is FeSO4·(NH4)2SO4.24H2O. It is a double salt having FeSO4 and (NH4)2SO4.


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483.

The coordination number and the oxidation state of the element 'M' in the complex [M(en)2(C2O4)] NO2 {where (en) is ethan 1, 2-diamine} are respectively

  • 6 and 3

  • 4 and 3

  • 6 and 2

  • 4 and 2


484.

In CsCl type structure the co-ordination of Cs+ and Cl- are:

  • 6, 6

  • 6, 8

  • 8, 8

  • 8, 6


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485.

The IUPAC name of K2[PtCl6] is:

  • hexachloroplatinate potassium

  • potassium hexachloroplatinate (IV)

  • potassium hexachloroplatinate

  • potassium hexachloroplatinum (IV)


486.

Calomel (Hg2Cl2) on reaction with ammonium hydroxide gives

  • HgO

  • Hg2O

  • NH2-Hg-Hg-Cl

  • HgNH2Cl


487.

The isomersim exhibited by following compounds [Co(NH3)6][Cr(CN)6] and [Cr(NH3)6(CN)6] is

  • ionisation isomerism

  • polymerisation isomersion

  • Linkage isomersim

  • Cooridination isomerism


488.

The increasing order of field strenght of ligands is

  • NH3< H2O< Cl-< CO< CN-

  • Cl-< H2O< NH3 < CN-< CO

  • Cl-< CO< CN-< H2O < NH3

  • CN-< CO< NH3< Cl- < H2O


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489.

Which one of the following does not exhibit geometrical isomerism?

  • Octahedral complex with formula [MX2L4]

  • Square planar complex with formula [MX2L2]

  • Tetrahedral complex with formula [MAB XL]

  • Octahedral complex with formula [MX2(L -L)2]


490.

Which of the following metal ions has a calculated magnetic moment value of ✓24. BM?

  • Mn2+

  • Fe2+

  • Fe3+

  • Co2+


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