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 Multiple Choice QuestionsMultiple Choice Questions

541.

In which of the following pairs are both the ions coloured in aqueous solution?

(At. no.: Sc = 21, Ti = 22, Ni = 28, Cu = 29, Co = 2)

  • Ni2+, Ti3+

  • Sc3+, Ti3+

  • Sc3+,Co2+

  • Sc3+,Co2+

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542.

Which of the following is not chiral 

  • 2-butanol

  • 2,3 -dibromo pentane

  • 3- bromopentane

  • 3- bromopentane

569 Views

543.

[Co(NH3)4(NO2)2]Cl exhibits:

  • linkage isomerism, ionisation isomerism and optical isomerism

  • Linkage isomerism, ionisation isomerism and geometrical isomerism

  • ionization isomerism, geometrical isomerism and optical isomerism

  • ionization isomerism, geometrical isomerism and optical isomerism

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544.

[Cr(H2O)6]Cl3 (at. no. of Cr = 24) has a magnetic moment of 3.83 BM, the correct distribution of 3d electrons in the chromium of the complex is:

  • 3 straight d subscript straight x squared minus straight y squared end subscript superscript 1 comma space 3 straight d subscript straight z squared end subscript superscript 1 comma space 3 straight d subscript xz superscript 1
  • 3 straight d subscript xy superscript 1 comma space 3 straight d subscript x squared minus y squared end subscript superscript 1 comma space 3 straight d subscript yz superscript 1
  • 3 straight d subscript xy superscript 1 comma space 3 straight d subscript zy superscript 1 comma space 3 straight d subscript zx superscript 1
  • 3 straight d subscript xy superscript 1 comma space 3 straight d subscript zy superscript 1 comma space 3 straight d subscript zx superscript 1
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545.

The number of unpaired electrons in a paramagnetic  diatomic molecule of an element with atomic number 6 is:

  • 2

  • 3

  • 4

  • 4

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546.

An example of a sigma bonded organometallic compound is :

  • Ruthenocene

  • Grignard's reagent

  • Ferrocene

  • Ferrocene

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547.

The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes: CoCl3.6NH3, CoCl3.5NH3, CoCl3.4NH3 respectively is

  • 1 AgCl, 3 AgCl, 2 AgCl

  • 3 AgCl, 1 AgCl, 2 AgCl

  • 3 AgCl, 2 AgCl, 1 AgCl

  • 3 AgCl, 2 AgCl, 1 AgCl

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548.

Correct increasing order for the wavelengths of absorption in the visible region for the complexes of Co3+ is

  • [Co(en)3]3+, [Co(NH3)6]3+, [Co(H2O)6]3+

  • [Co(H2O)6]3+, [Co(en)3]3+, [Co(NH3)6]3+

  • [Co(H2O)6]3+, [Co(NH3)6]3+, [Co(en)3]3+

  • [Co(H2O)6]3+, [Co(NH3)6]3+, [Co(en)3]3+


A.

[Co(en)3]3+, [Co(NH3)6]3+, [Co(H2O)6]3+

The order of the ligand in the spectrochemical series
H2O < NH3< en
Hence, the wavelength of the light observed will be in the order

[Co(H2O)6]3+, [Co(NH3)6]3+, [Co(en)3]3+
Thus, wavelength absorbed will be in the opposite order
[Co(en)3]3+, [Co(NH3)6]3+, [Co(H2O)6]3+

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549.

Pick out the correct statement with respect
[Mn(CN)6]3–

  • It is sp3d2 hybridised and octahedral

  • It is sp3d2 hybridised and tetrahedral

  • It is d2sp3 hybridised and octahedral

  • It is d2sp3 hybridised and octahedral

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550.

Match the metal ions given in Column I with the spin magnetic moments of the ions given in Column II and assign the correct code :

Column I Column II
a. Co3+ i. 8 BM
b. Cr3+ ii. 35 BM
c. Fe3+ iii. 3 BM
d. Ni2+ iv. 24 BM
    v. 15 BM

  • a b c d
    iv v ii i
  • a b c d
    i ii iii iv
  • a b c d
    iii v i ii
  • a b c d
    iv i ii iii

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