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 Multiple Choice QuestionsMultiple Choice Questions

591.

Assertion:

 is named as tetrakis (ethylene-diammine) μ-hydroxo-m-imido dicobalt (III) ion.

Reason : In naming polynuclear complexes i.e., containing two or more metal atoms joined by bridging ligands, the word μ is added with hyphen before the name of such ligands.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


592.

Which of the following is considered as an anticancer species?


593.

Assertion : Al forms [AlF6]3- but B does not form [BF6]3-.

Reason : B does not react with fluorine.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false


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594.

Which of the following metal ions will form complexes with the same magnetic moment and geometry irrespective of the nature of ligands?

  • Ni2+

  • Fe2+

  • Cu2+

  • Co2+


C.

Cu2+

Cu2+ will form complexes with the same magnetic moment and geometry. In presence of either strong field or weak field the number of unpaired electron remains the same in case of Cu2+ ion.

Cu → 3d104s1

Cu2+ → 3d9 

           


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595.

Wavelength of red light is absorbed by the complex

  • [Cu(CN)4]2-

  • [Cu(NH3)4]2+

  • CuSO4

  • Cu(CN)2


596.

In the change[Cu(H2O)6F]2+ HCl [CuCl(H2O)5]+, the colour changes from

  • blue to green

  • blue to pink

  • pink to green

  • pink to blue


597.

Assertion : In high spin situation, configuration
of d5 ions will be t2g3, eg2.

Reason : In high spin situation, pairing energy is less than crystal field energy.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


598.

Which of the following does not contain any coordinate bond?

  • H3O+

  • BF4-

  • HF2-

  • NH4+


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599.

The pair in which both species have same magnetic moment (spin only value) is

  • [Cr(H2O)6]2+,[CoCl4]2+

  • [Cr(H2O)6]2+,[Fe(H2O)6]2+

  • [Mn(H2O)6]2+, [Cr(H2O)6]2+

  • [CoCl4]2-, [Fe(H2O)6]2+


600.

Which gives nucleophilic addition most easily :

  • CH3CHO

  • CH3CH2CHO

  • (CH3)2CHCHO

  • HCHO


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