5.Calculate the emf of the cell in which the following reaction takes place: Ni(s) + 2Ag+ (0.002 M) Ni2+ (0.160 M) + 2Ag(s) Given that
Answer:
or
The equation is also written as
or
= 1.05 V – 0.0295 x log 80
= 1.05 V – 0.0295 x 1.9031
= 1.05 V – 0.056 = 0.99 V.
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6.The cell in which the following reaction occurs: 2Fe3+ (aq) + 2I–(aq) 2Fe2+ (aq) + I2(s) has E0cell = 0.236 V at 298 K. Calculate the standerd Gibbs energy and the equilibrium constance of the cell reaction.
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7.Why does the conductivity of a solution decrease with dilution?
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8.Suggest a way to determine the Λ°m value of water.
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Long Answer Type
9.
The molar conductivity of 0.025 mol L–1 methanoic acid is 46.1 S cm2 mol–1. Calculate its degree of dissociation and dissociation constant. Give λ°(H+) = 349.6 S cm2 mol–1 and λ° (HCOO– ) = 54.6 s cm2 mol–1.
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10.If the current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons flow through the wire?