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101. The standard reduction potential values of three metal cations Xa⁺, Yb⁺ and Zc⁺are + 0.52, – 3.03, – 1.18 V respectively. Arrange the corresponding metals, in the order of their increasing reducing power.

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102. Explain with the help of a diagram the effect of change in concentration of solution on the molar conductance of (i) a weak electrolyte, (ii) a strong electrolyte.

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103. State two advantages of H₂O fuel cell over ordinary cell.

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104. What happens during corrosion of a metal? State the electrochemical basis of corrosion of iron.

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105.

{E^{0}}_{{Ni}^{2 +} / Ni} and {E^{0}}_{{Cu}^{2 +} / Cu}

are -0.25 V and + 0.34 respectively at 298 K. Formulate the self operating galvanic cell for this electrode pair. What reaction takes place in its operation? How is the ΔG° for this reaction related to the cell e.m.f.?

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106. How does molar conductance of a strong electrolyte vary with its concentration in solution?

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107. How does molar conductance of a weak electrolyte vary with its concentration in solution?

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Long Answer Type

108. What do you understand by standard potential of a half-cell? How is the electrode potential of a half-cell determined?

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Short Answer Type

109. Define molar conductivity of an electrolytic solution. Mention the effect of temperature on molar conductivity.

Molar conductivity is defined as the electrolytic conductivity power of all the ions furnished by 1 mol of the electrolyte at a given concentration in solution. It is given as

Λ_{m} = \frac{k}{Cm}

where A_m = Molar conductivity.
k = Specific conductivity. Cm = Concentration in molar per litre.

Effect of temperature on molar conductivity. The speed of movement of ions increases with an increase in temperature. Therefore, molar conductivity increases with temperature.

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110. Write anode and cathode reactions from electrolysis of water. How much charge will be transported for the decomposition of 3.6 g of H₂O? [F = 96500 C mol^–1]

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