Calculate the cell e.m.f. at 25° C for the following cell:Mg(

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171. Conductivity of 0.00241 M acetic acid is 7.896 x 10–5 S cm–1. Calculate its molar conductivity, if Λ° for acetic acid is 390.5 S cm2 mol–1, what is its dissociation constant?
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172. Write the Nernst equation and calculate the emf of the following cell at 298 K : Cu(s) | Cu2+ (0.130 M) || Ag+ (1.00 x 10–4 M) | Ag(s)
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173. (a) Calculate the electrode potential of silver electrode dipped in 0.1 M solution of silver nitrate at 298 K assumimg AgNO3 to be completely dissociated. The standard electrode potential of Ag+/Ag is 0.80 V at 298 K.
(b) At what concentration of silver ions will this electrode have a potential of 8.0 V?
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174. The standard reduction potential for the Zn2+ (aq) | Zn(s) half cell is 0.76 V. Write the reactions occurring at the electrodes when coupled with standard hydrogen electrode (SHE).
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175.

Can a nickel spatula be used to stir the solution of CuSO4? Support your answer with reason. (E°Ni2+/Ni = – 0.25 V, E°Cu2+/Cu = + 0.34 V)

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 Multiple Choice QuestionsLong Answer Type

176.

Calculate the e.m.f. of the cell in which the reaction is
Mg(s) + 2Ag+(aq)  Mg2+(aq) + 2Ag(s)When    Mg2+ = 0.130 Mand           Ag+ = 1.0 × 10-4M.    [Given EMg2+/Mg = -2.37 V and E°Ag+/Ag = 0.80 V]

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177. Calculate the cell e.m.f. at 25° C for the following cell:
Mg(s) | Mg2+ (0.01 M) || Sn2+ (0.1 M) | Sn (s)
[Given E°Mg2+/Mg = – 2.34 V, E°Sn2+/Sn = – 0.136V, 1 F = 96,500 C mol–1]
Calculate the maximum work that can be accomplished by the operation of this cell.


Mg(s) | Mg2+ (0.01 M) || Sn2+ (0.1 M) | Sn(s)
Mg(s) → Mg2+ (aq) + 2e
(oxidation at anode)
Sn2+(aq) + 2e → Sn(s)
(reduction at cathode)

Mg(s) | Mg2+ (0.01 M) || Sn2+ (0.1 M) | Sn(s)Mg(s) → Mg2+ (aq) +

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178.

Calculate the cell emf at 25° C for the following cell:
Ni(s) | Ni2+ (0.01 M) || Cu2+ (0.1 M) | Cu(s)
[Given E°Ni2+/Ni = – 0 25 V, E° Cu = + 0.34 V, 1 F = 96500]
Calculate the maximum work that can be accomplished by operation of this cell.

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179.

The emf of a cell corresponding to the reaction
Zn(s) + 2H+ (aq) → Zn2+ (0.1 M) + H2(g) (1 atm) is 0.28 V at 15° C.Write the half cell reactions and calculate the pH of the solution at the hydrogen electrode.

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180. Using the standard electrode potentials given in the table 3.1(in NCERT), predict if the reaction between the following is feasible:
(i) Fe3+ (aq) and I (aq)
(ii) Ag+ (aq) and Cu(s)
(iii) Fe3+ (aq) and Br(aq)
(iv) Ag(s) and Fe3+(aq)
(v) Br2(aq) and Fe2+(aq)
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