What is a galvanic cell? What type of reactions give rise to elec

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 Multiple Choice QuestionsShort Answer Type

231. Which factor makes secondary cells more acceptable as a source of power?
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232. Write Nernst equation for single electrode potential.
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233. Why is the equilibrium constant k related to only E°cell and not Ecell.
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234. How does the molar conductivity of KCl solution vary with increasing concentration?
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235. Give an example of fuel cell.
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236. Write the symbolic notation for standard hydrogen electrode and its potential.
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237. What is a galvanic cell? What type of reactions give rise to electric current in a galvanic cell and how?


A galvanic cell (left) transforms the energy released by a spontaneous redox reaction into electrical energy that can be used to perform work. The oxidative and reductive half-reactions usually occur in separate compartments that are connected by an external electrical circuit.

Oxidation half reaction:
Y ----> Y+ +e-

Reduction half reaction:
Z + e- ----> Z-

overall cell reaction

Y+Z ------> Y+ + Z- (G<0)

A second connection that allows ions to flow between the compartments (shown here as a vertical dashed line to represent a porous barrier) is necessary to maintain electrical neutrality. The potential difference between the electrodes (voltage) causes electrons to flow from the reductant to the oxidant through the external circuit, generating an electric current.

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238. What information is conveyed by the cell rotation given below?
Cu(s) | Cu2+ (aq) (0.1 M) || Ag+ (aq) (0.2 M) | Ag(s)
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239. What is a salt bridge and what function does it save in a galvanic cell?
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240. What is meant by ‘standard electrode potential’ on the hydrogen scale?
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