What is a salt bridge and what function does it save in a galvani

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 Multiple Choice QuestionsShort Answer Type

231. Which factor makes secondary cells more acceptable as a source of power?
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232. Write Nernst equation for single electrode potential.
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233. Why is the equilibrium constant k related to only E°cell and not Ecell.
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234. How does the molar conductivity of KCl solution vary with increasing concentration?
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235. Give an example of fuel cell.
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236. Write the symbolic notation for standard hydrogen electrode and its potential.
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237. What is a galvanic cell? What type of reactions give rise to electric current in a galvanic cell and how?
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238. What information is conveyed by the cell rotation given below?
Cu(s) | Cu2+ (aq) (0.1 M) || Ag+ (aq) (0.2 M) | Ag(s)
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239. What is a salt bridge and what function does it save in a galvanic cell?


A salt bridge is a U-shaped device containing concentrated solution of an inert electrolyte like KCl, KNO3, etc.or a solidified solution of those electrolytes in agar-agar solution and gelatin. It connects the oxidation and reduction half-cells of a galvanic cell. The inert electrolytes present do not take part in redox reaction of the cell and dont react with the electrolyte that has been used.

 

As electrons leave one half of a galvanic cell and flow to the other, a difference in charge is built up. If no salt bridge were used, this increasing charge difference would eventually prevent further flow of electrons. The salt bridge solves these problems. It has two main functions:

1. To allow the flow of ions from one solution to another without mixing of the two solutions and completing the electrical circuit.

2. To maintain the electical neutrality of the solutions in the two half cells.

 

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240. What is meant by ‘standard electrode potential’ on the hydrogen scale?
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