361.

Electrolyte	KCl	KNO3	HCl	NaOAc	NaCl
∧∞S cm2 mol-	149.9	145.0	426.2	91.0	126.5

Calculate ∧^∞_HOAc Using appropriate molar conductances of the electrolytes listed above at infinite dilution in H₂O at 25°C

• 517.2

• 552.7

• 390.7

• 390.7

Calomel ₍Hg₂Cl2) on reaction with ammonium hydroxide gives

• HgNH₂Cl

• NH₂ – Hg – Hg – Cl

• Hg₂O

• Hg₂O

Which among the following factors is the most important in making fluorine the strongest oxidizing halogen?

• Electron affinity

• Bond dissociation energy

• Hydration enthalpy

• Hydration enthalpy

In hydrogen-oxygen fuel cell, combustion of hydrogen occurs to

• generate heat

• remove adsorbed oxygen from electrode surfaces

• produce high purity water

• produce high purity water

Consider the following E° values


Under standard conditions the potential for the reaction
Sn(s) + 2Fe³⁺(aq) → 2Fe²⁺(aq) + Sn²⁺(aq) is

• 1.68 V

• 0.63 V

• 0.91 V

• 0.91 V

The standard e.m.f of a cell, involving one electron change is found to be 0.591 V at 25°C. The equilibrium constant of the reaction is (F = 96,500 C mol-1: R = 8.314 JK^-1 mol^-1)

• 1.0×10¹

• 1.0×10³⁰

• 1.0×10³⁰

• 1.0×10³⁰

The limiting molar conductivities Λ° for NaCl, KBr and KCl are 126, 152 and 150 S cm² mol^-1 respectively. The Λ° for NaBr is

• 128 S cm² mol^-1

• 302 S cm² mol^-1

• 278 S cm² mol^-1

• 278 S cm² mol^-1

In a cell that utilises the reaction Zn(s) + 2H⁺ (aq) → Zn²⁺(aq) + H₂(g) addition of H₂SO₄ to cathode compartment, will

• lower the E and shift equilibrium to the left

• increases the E and shift equilibrium to the left

• increase the E and shift equilibrium to the right

• increase the E and shift equilibrium to the right

The  values for Cr, Mn, Fe and Co are – 0.41, +1.57, + 0.77 and +1.97 V respectively. For which one of these metals the change in oxidation state form +2 to +3 is easiest?

• Cr

• Co

• Fe

• Fe

How long (approximate) should water be electrolysed by passing through 100 amperes current so that the oxygen released can completely burn 27.66 g of diborane? (Atomic weight of B = 10.8 u)

• 1.6 hours

• 6.4 hours

• 0.8 hours

• 3.2 hours