The standard electrode potentials of Ag+/Ag is +0.80V and Cu+/Cu is +0.34 V. These electrodes are connected through a salt bridge and if:
copper electrode acts as a cathode then E° cell is +0.46 V
silver electrode acts as anode then E° cell is -0.34 V
copper electrode acts as anode then E° cell is +0.46 V
silver electrode acts as a cathode then E° cell is -0.34 V
If three Faradays of electricity is passed through the solutions of AgNO3, CusO4 and AuCl3, the molar ratio of the cations deposited at the cathodes will be :
1 : 1 : 1
1 : 2 : 3
3 : 2 : 1
6 : 3 : 2
E - 0.34 V; E = 0.76 V. A Daniel cell contains 0.1 M ZnSO4 solution and 0.01M CuSO4 solution at its electrodes. EMF of the cell is:
1.10 V
1.04 V
1.16 V
1.07 V
When electric current is passed through an ionic hydride in molten state :
hydrogen is liberated at anode
hydrogen is liberated at cathode
no change takes place
hydride for migrates towards cathode
A.
hydrogen is liberated at anode
The ionic hydrides conduct electricity in molten state and liberate H2 at anode.
CaH2 + 2H2O → Ca(OH)2 + 2H2 ↑
What is potential of platinum wire dipped into a solution of 0.1 M in Sn2+ and 0.01 M in Sn4+ ?
E°
E° + 0.059
E° +
E° - 0.059
Zn(s) | Zn2+(aq)|| Cu2+(aq) | Cu(s) is :
(anode) (cathode)
Weston cell
Daniel cell
Faraday cell
Standard cell
When 1 F of electricity is passed through acidulated water, O2 evolved is
11.2 dm3
5.6 dm3
22.4 dm3
1.0 dm3
The oxidation potential values of A, B, C and D are -0.03 V, +0.108 V, -0.07 V and +0.1 V respectively. The non-spontaneous cell reaction takes place between
A and B
Band D
D and A
B and C