A device that converts energy of combustion of fuels like hydrog

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 Multiple Choice QuestionsMultiple Choice Questions

581.

Which of the following graphs between molar conductivity ∧versus √C is correct?

 


582.

The pressure of H2 required to make the potential of H2-electrode zero in pure water at 298 K is

  • 10-12 atm

  • 10-10 atm

  • 10-4 atm

  • 10-4 atm

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583.

A device that converts energy of combustion of fuels like hydrogen and methane, directly into electrical energy is known as

  • fuel cell

  • electrolytic cell

  • dynamo

  • dynamo


A.

fuel cell

A fuel cell is a device that converts the energy of combustion of fuels like hydrogen and methane, directly into electrical energy. 
Electrolytic cell converts electrical energy into chemical energy. Dynamo is an electrical generator that produces direct current with the use of a commutator.
Ni-Cd cell is the type of rechargeable battery which consists of a cadmium anode and a metal grid containing NiO2 acting as a cathode.

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584.

When 0.1 mol MnO42- is oxidised, the quantity of electricity required to completely oxidise MnO42- to MnO42- is

  • 95600C

  • 2 x 96500C

  • 9650 C

  • 9650 C

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585.

Using the Gibbs energy change, ΔG0 = +63.3 KJ for the following reaction,
Ag2CO3 (s) r2Ag+ (aq) + CO32- (aq)
the Ksp of Ag2CO3 (s) in water at 250 C is (R= 8.314 JK-1 mol-1)

  • 3.2 x 10-26

  • 8.0 x 10-12

  • 2.9 x 10-3

  • 2.9 x 10-3

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586.

At 250 molar conductance of 0.1 molar aqueous solutions of ammonium hydroxide is 9.54 ohm-1 cm2 mol-1 and at infinite dilution, its molar conductance is 238 ohm-1 cm2 mol-1. The degree of ionisation of ammonium hydroxide at the same concentration and temperature is 

  • 2.080%

  • 20.800%

  • 4.008%

  • 4.008%

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587.

A button cell used in watches functions as following
Zn space left parenthesis straight s right parenthesis space plus Ag subscript 2 straight O space left parenthesis straight s right parenthesis space plus straight H subscript 2 straight O space left parenthesis straight l right parenthesis space rightwards harpoon over leftwards harpoon space 2 space Ag space left parenthesis straight s right parenthesis space plus Zn to the power of 2 plus end exponent space left parenthesis aq right parenthesis space plus 2 OH to the power of minus space left parenthesis aq right parenthesis
If space half minus cell space potentials space are
Zn to the power of 2 plus end exponent space left parenthesis aq right parenthesis space plus 2 straight e to the power of minus space rightwards arrow space Zn left parenthesis straight s right parenthesis semicolon space straight E to the power of 0 equals space minus 0.76 space straight V
Ag subscript 2 straight O space left parenthesis straight s right parenthesis space plus straight H subscript 2 straight O space left parenthesis straight l right parenthesis space plus 2 straight e to the power of minus rightwards arrow 2 Ag space left parenthesis straight s right parenthesis space plus 2 OH to the power of minus space left parenthesis aq right parenthesis space left parenthesis straight E to the power of 0 space equals space 0.34 space straight V right parenthesis
The cell potential will be

  • 1.10 V

  • 0.42 V

  • 0.84 V

  • 0.84 V

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588.

Limiting molar conductivity  of NH4OH (i.e., straight capital lambda with straight o on top subscript m left parenthesis N H subscript 4 O H right parenthesis space end subscript is equal to 

  • straight capital lambda with straight o on top subscript m space left parenthesis N H subscript 4 C l right parenthesis space end subscript space plus straight capital lambda with straight o on top subscript m space left parenthesis N a C l right parenthesis space end subscript minus space straight capital lambda with straight o on top subscript m space left parenthesis N a O H l right parenthesis space end subscript
  • straight capital lambda with straight o on top subscript m space left parenthesis N a O H right parenthesis space end subscript space plus straight capital lambda with straight o on top subscript m space left parenthesis N a C l right parenthesis space end subscript minus space straight capital lambda with straight o on top subscript m space left parenthesis N H subscript italic 4 C l right parenthesis space end subscript
  • straight capital lambda with straight o on top subscript m space left parenthesis N H subscript 4 O H right parenthesis space end subscript space plus straight capital lambda with straight o on top subscript m space left parenthesis N H subscript italic 4 C l right parenthesis space end subscript minus space straight capital lambda with straight o on top subscript m space left parenthesis HCl right parenthesis space end subscript
  • straight capital lambda with straight o on top subscript m space left parenthesis N H subscript 4 O H right parenthesis space end subscript space plus straight capital lambda with straight o on top subscript m space left parenthesis N H subscript italic 4 C l right parenthesis space end subscript minus space straight capital lambda with straight o on top subscript m space left parenthesis HCl right parenthesis space end subscript
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589.

Standard reduction potentials of the half-reactions are given below.

F2 (g) +2e- → 2F- (aq) ;  Eo = +2.85 V
Cl2 (g) +2e- →2Cl- (aq) ; Eo = +1.36V
Br2 (l) +2e- → 2Br(aq) ; Eo = +1.06 V
I2 (s) +2e- →2I- (aq); Eo = +0.53 V

The strongest oxidising and reducing agents respectively are

  • F2 and I-

  • Br2 and Cl-

  • Cl2 and Br-

  • Cl2 and Br-

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590.

Molar conductivities (Λom) at infinite dilution of NaCl, HCl and CH3COONa are 126.4, 425.9 and 91.0 S Cm2 mol-1 respectively. Λom for CH3COOH will be

  • 425.5 S cm2 mol-1

  • 180.5 S cm2 mol-1

  • 290.8 S cm2 mol-1

  • 290.8 S cm2 mol-1

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