What is the maximum concentration of equimolar solutions of ferr

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 Multiple Choice QuestionsLong Answer Type

321.

If 20 ml of 1·5 × 10–5 M BaClsolution is mixed with 40 ml of 0·9 × 10–5MNa2SO4 solution, will a precipitate get formed? Ksp for BaSO4 = 0·1 × 10–10.

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322.

If 25.0 cm3 of 0.50 M - Ba(NO3)are mixed with 25·0 cm3 of 0·0220M-NaF, will any BaF2 precipitate  [Ksp of Ba F2 is 1·7 × 10–6 at 298 K.]

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323.

Equal volumes of 0.002M solutions of sodium iodate and cupric chlorate are mixed together. Will it lead precipitation of copper iodate? (For cupric iodate Ksp = 7·4 × 10–8).

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324. What is the maximum concentration of equimolar solutions of ferrous sulphate and sodium sulphide so that when mixed in equal volumes, there is no precipitation of iron sulphide? (For iron sulphide, Ksp = 6·3 × 10–18).


Let the concentration of both FeSO4 and Na2S solutions before mixing = x mol L= xM

The solubility equilibrium of iron sulphide may be represented as,


Now, Fe2+ ions are to be provided by FeSOand S2– ions and are to be provided by Na2S, as a result of dissociation.



Since equal volumes of the two solutions have been mixed, the concentration of the solutions as well as of ions on mixing will be reduced to half i.e.
 
Since oh mixing, there is no precipitation of iron sulphide, therefore,
Ionic product = Solubility product


The maximum concentration of both the solutions is 5·02 × 10–9M
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 Multiple Choice QuestionsShort Answer Type

325.

The concentration of sulphide ion in 0·1M HCl solution saturated with hydrogen sulphide is 1·0 × 10–19M. If 10 mL of this solution is added to 5 mL of 0·04M solution of FeSO4, MnCl2, ZnCl2 and CaCl2, in which solutions precipitation will take place? Given Ksp for FeS = 6·3 × 10–18, MnS = 2·5 × 10–13, ZnS =1·6 × 10–24and CdS = 8·0 × 10–27.

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 Multiple Choice QuestionsLong Answer Type

326.

The values of Ksp of two sparingly soluble salts Ni(OH)2 and AgCN are 2·0 × 10–15 and 6 × 10–17 respectively. Which salt is more soluble ? Explain

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327.

The solubility product constant of Ag2CrO4 and AgBr are 1·1 × 10–12 and 5·0 × 10–13 respectively. Calculate the ratio of the molarities of their saturated solutions.

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 Multiple Choice QuestionsShort Answer Type

328. How do solubility product and ionic product help in predicting the nature of solution? What is the significance of ionic product of water ?
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329.

Flow will you purify an impure sample of sodium chloride containing water soluble impurities?

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330. What is the function of dilute HCl in group II analysis?
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