In the formation of SO3 according to following equilibrium 2SO2 + O2 2SO3 + heat, which conditions favour the formation of SO3?
Low pressure
Low concentration of oxygen
Low temperature and use of catalyst
High temperature without using catalyst
Which of the following mixtures forms an acid buffer?
NaOH + HCl
CH3COOH + CH3COONa
NH4OH + NH4Cl
H2CO3 + (NH4)2CO3
When NH4Cl is added to NH4OH solution, the dissociation of ammonium hydroxide is reduced. It is due to
common ion effect
hydrolysis
oxidation
reduction
pH of a solution is 4. The hydroxide ion concentration of the solution would be
10-4
10-10
10-2
10-12
B.
10-10
Given,
pH = 4
pH = -log [H+]
4 = -log [H+]
[H+] = 1 × 10-4
At 25°C,
[H+][OH-] = 1 × 10-14
1 × 10-4 [OH-] = 1 × 10-14
[OH-] =
[OH-] = 1 × 10-10
Heat of neutralisation of NH4OH and HCl is
equal to 13.7 kcal
more than 13.7 kcal
less than 13.7 kcal
more than one is correct
A chemical reaction is in equilibrium when
the reactants are completely transformed into products
the rate of forward reaction is equal to the rate of backward reaction
the formation of products is minimised
equal amount of reactants and products are present
For the following gaseous reaction, H2 + I2 2HI, the equilibrium constant
Kp > Kc
Kp< Kc
Kp= Kc
Kp= 1/Kc
According to Le-Chatelier's principle which of the following factors influence a chemical system?
Concentration only
Pressure only
Temperature only
Concentration, pressure and temperature
The pH of water decreases with?
increase in temperature
increase in pressure
decrease in temperature
decrease in pressure