1.0 L of 1.0 M solution of sodium hydroxide is neutralised by 1.0

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 Multiple Choice QuestionsMultiple Choice Questions

581.

In the equilibrium reaction 2HI (g)  H2 + I2 which of the following expressions is true?

  • Kp = Kc

  • Kc = 2Kp

  • Kp > Kc

  • Kc = Kp (RT)2


582.

Strongest Bronsted base among the following anions is:

  • ClO-

  • ClO2-

  • ClO3-

  • ClO4-


583.

1.1 moles of A and 2.2 moles of B are mixed in a container of one litre volume to obtain the equilibrium A + 2B  2C + D.

At equilibrium 0.2 moles of C are formed. The equilibrium constant for the above reaction is

  • 0.001

  • 0.002

  • 0.003

  • 0.004


584.

In which solution/ solvent the solubility of AgCl is minimum?

  • 0.01 M NaCl

  • 0.01 M CaCl2

  • Pure water

  • 0.001 M AgNO3


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585.

Which one of the following salts gives an acidic solution in water?

  • CH3COONa

  • NH4Cl

  • NaCl

  • CH3COONH4


586.

Which of the following exhibits highest solubility in water?

  • NH3

  • PH3

  • AsH3

  • SbH3


587.

The chemical decomposition of XY2 occurs as XY2(g)  XY (g) + Y(g). The initial vapour pressure of XY2 is 600 mm of mercury and at equilibrium it is 800 mm of mercury. Find out the value of K for this reaction when the volume of the system remains constant.

  • 50

  • 100

  • 166.6

  • 150


588.

The degree of ionisation of decinormal solution of CH3COOH is 1.3%. If the log of 1.3 is 0.11, the pH of this solution is

  • 2.89

  • 3.89

  • 4.89

  • 0.89


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589.

A buffer solution is obtained by mixing 10 mL of 1.0M CH3COOH and 20mL of 0.5M CH3COONa and it is diluted to 100mL using distilled water. pKa of CH3COOH is 4.76. The pH of this buffer solution is 

  • 2.76

  • 3.76

  • 4.76

  • 0.76


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590.

1.0 L of 1.0 M solution of sodium hydroxide is neutralised by 1.0 L of 1.0 M of methanoic acid. If the heat of formation of water is X, the neutralisation energy of above reaction is

  • less than X

  • more than X

  • equal to X

  • None of the above


A.

less than X

The heat of neutralisation of a strong acid against a strong base is always constant (13.7 kcal).

H+ + OH- H2O , ΔH = 13.7 kcal

In case of neutralisaton of weak acid (methanoic acid) against a strong base (sodium hydroxide), since a part of the evolved heat is used up in ionising the weak acid. Thus, it is always less than 13.7 kcal mol-1 (i.e., X).


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