What is the solubility of silver bromide in one litre of 0.4 mola

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 Multiple Choice QuestionsMultiple Choice Questions

621.

An example of a salt that will not hydrolyse is

  • CH3COONH4

  • CH3COOK

  • NH4Cl

  • KCl


622.

20 mL of 0.25 N strong acid and 30 mL 0·2 N of strong base are mixed; the resulting solution is

  • 0.02 N acidic

  • 0.025 N basic

  • 0.02 N basic

  • 0.025 N acidic


623.

The rate of forward reaction is two times that of reverse reaction at a given temperature and identical concentration. K

  • 2.5

  • 2.0

  • 0.5

  • 1.5


624.

Ammonium ion is

  • neither an acid nor base

  • both an acid and a base

  • a conjugate acid

  • a conjugate base


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625.

A is an aqueous acid; B is an aqueous base. They are diluted separately, then

  • pH of A decreases and pH of B increases

  • pH of A increases and pH of B decreases till pH in each case is 7

  • pH of A and B increase

  • pH of B and A decrease


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626.

What is the solubility of silver bromide in one litre of 0.4 molar NH3 solution (K =10x108)?

  • 80 × 10-6 mol

  • 2.8 × 10-3 mol

  • 115 × 10-3 mol

  • 0.98 g


C.

115 × 10-3 mol

Let solubility by AgBr be x M Thus, [Br] = xM and [Ag+] = yM as Ag+ react with NH3 to form a examples

  AgBr  Ag+(a) + Br(aq)Ksp= [Ag+][Br-] = yxSmee, the formation constant (Kf) of the complex is very high, assume thatwhole Ag+ formed is consumed.Ag+ + 2NH3  Ag(NH3)2+x            0.4            0.4-2x        xAg(NH3)2+  Ag+(aq) + 2NH3   x                                        0.4-2xx-y                 y                  0.4-2x+2yKd=Ag+NH32Ag(NH3)2+ =y(0.4-2x+2y)2x-yx - y = x since Kd(1 ×10-8 is low ) and x<<0.4Kd(1 ×10-8)=y(0.4)2xsolving for x then x=115 × 10-3M


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627.

ZXM2He4 → 15P300n1. Then

  • Z = 12, M = 27

  • Z = 13, M = 27

  • Z = 12, M = 17

  • Z = 13, M = 28


628.

Which expression has no physical significance?

  • GTp

  • GpT

  • (G)Tp

  • (G)pT


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629.

Heat of neutralisation of weak acid and strong base is less than the heat of neutralisation of strong acid and strong base due to

  • energy has to be spent for the total dissociation of weak acid

  • salt of weak acid and strong base is not stable

  • incomplete dissociation of weak acid

  • incomplete neutralisation of weak acid


630.

A colourless crystalline salt 'x' is soluble in dilute HCl. On adding NaOH solution, it gives a white precipitate which is insoluble in excess of NaOH. 'x' is

  • Al2(SO4)3

  • ZnSO4

  • MgSO4

  • SnCl2


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