The true statement for the acids of phosphorus, H3PO2 H3PO3 and H

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 Multiple Choice QuestionsMultiple Choice Questions

891.

If the equilibrium constant of the reaction of weak acid HA with strong base is 109 then pH of 0.l M NaA is :

  • 5

  • 9

  • 7

  • 8


892.

Which of the following compounds is the weakest Bronsted base ?


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893.

The true statement for the acids of phosphorus, H3PO2 H3PO3 and H3PO4 is

  • the order of their acidity is H3PO4 > H3PO3 > H3PO2

  • all of them are reducing in nature

  • all of them are tribasic acids

  • the geometry of phosphorus is tetrahedral in all the three.


D.

the geometry of phosphorus is tetrahedral in all the three.

H3PO2, H3PO3 and H3PO4 contain one, two and three ionisable hydrogen atoms respectively.

H3PO2 H+ + H2PO2-

H3PO3  H+ H2PO3-  H+ + HPO32-

H3PO4  H+ + H2PO4-  H+ + HPO42-

                                     H+ + PO43-

But there is very little difference in acidity. In H3PO2, H3PO3 and H3PO4, P is sp3 hybridised in all. Therefore, all are tetrahedral.


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894.

Assertion : H3BOis a weak acid.

Reason : Water extracts the proton of H3BO3.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false

  • If both assertion and reason are false.


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895.

The ionisation percentage of 0.2 M HCN the solution is 0.02%. What will be the value of ionisation constant ?

  • 8 x 10-5

  • 8 x 10-9

  • 8 x 10-7 

  • 8 x 10-3


896.

Which one act as Bronsted acid as well as Bronsted base?

  • Cl-

  • OH-

  • HCl

  • H2O


897.

If the pH of HCl soltion is 2 then the molar concentration of this will be :

  • 0.01 M

  • 2 M

  • 0.4 M

  • 0.02 M


898.

BF3 molecule is :

  • Lewis base

  • Lewis acid

  • Neutral

  • None of these


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899.

NO212 O2  NO3 .......K1

2NO2 + O2  2NO3 ........K2

For the above reaction the relation between equilibrium constant is :

  • K2 = (K1)2

  • K21K1

  • K21K12

  • K1 = K2


900.

The strongest Bronsted base is :

  • HClO2-

  • HClO-

  • HClO3-

  • HClO4


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