Arrange the nucleophilicity (rate of SN2 reactivity) of
(i) H2O, OH–, CH3COO- and CH3O-
(ii) NH3 and PH3.
Arrange the following compounds according to their relative reactivity with the reagents mentioned against them.
(a) C6H5CH2CH2Br, C6H5CHBrCH3 and C6H5CH = CHBr with alcoholic silver nitrate.
(b) C6H5CH2Br, n-C6H13 Br and C6H5Br with ale. AgNO3 or with KCN.
(c) t-Butyl chloride, sec-butyl chloride and CCl4 with ale. silver nitrate.
(d) m-Nitro chlorobenzene, 2, 4-dinitro-chlorobenzene and p-nitro chlorobenzene with sodium ethoxide.