Important Questions of Haloalkanes and Haloarenes Chemistry | Zigya

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551.

Excess of copper in toxic proportions in plants/animals can be removed by chelating with

  • EDTA

  • ethane-1,2-diamine

  • oxalate ion

  • D-pencillamine


552.

Which will undergo SN2 reaction fastest among the following halogen compounds?

  • CH3CH2F

  • CH3CH2Cl

  • CH3CH2Br

  • CH3CH2I


553.

The alkyl halide that undergoes SN1 reaction more readily is

  • t-butyl bromide

  • n-propyl bromide

  • vinyl bromide

  • isopropyl bromide


554.

An alkyl halide (R X) reacts with Na to form 4, 5-diethyloctane. Compound R X is

  • CH3(CH2)3Br

  • CH3(CH2)2CH(Br)CH2CH3

  • CH3(CH2)3CH(Br)CH3

  • CH3(CH2)5Br


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555.

Which of the following is a double base propellant ?

  • Methyl nitrate and nitromethane

  • Nitroglycerine and nitrocellulose

  • Kerosine and alcohol

  • Acrylic rubber and liquid N2O4


556.

Which one of the following compounds is capable of existing in a mesa form?

  • 2,4-dibromopentane

  • 3,3-dibromopentane

  • 4-bromo-2-pentanol

  • 3-bromo-2-pentanol


557.

Which of the following is not true of carbanions?

  • The carbon carrying the charge has eight valence electrons

  • They are formed by heterolytic fission

  • They are paramagnetic

  • The carbon carrying the charge is sp3 hybridised


558.

The SN1 reactivity of the following halides will be in the order

(i) (CH3)3CBr

(ii) (C6H5)2CHBr

(iii) (C6H5)2C(CH3)Br

(iv) (CH3)2CHBr

(v) C2H5Br

  • (iii) > (ii) > (i) > (iv) > (v)

  • (v) > (iv) > (i) > (ii) > (iii)

  • (ii) > (i) > (iii) > (v) > (iv)

  • (v) > (i) > (ii) > (iv) > (iii)


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559.

Which of the following does not answer iodoform test?

  • n-butyl alcohol

  • sec-butyl alcohol

  • Acetophenone

  • Acetaldehyde


560.

Aniline on treatment with NaNO2 in HCl at 0°C followed by treatment with alkaline β-naphthol gives:

  • a violet solution

  • a red solution

  • a green solution

  • a blue precipitate


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