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 Multiple Choice QuestionsShort Answer Type

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271.

Arrange the following compounds in increasing order of SN1 , respectively.

(CH3)3CCI, C6H5(CH3)2Cl, CH3CH2CH2Cl


CH3CH2CH2Cl < (CH3)3C.Cl < C6H5C(CH3)2Cl

(The is due to the stability of carbocation intermediate and resonance effects of phenol).
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272.

What are the structure of the possible isomes of dichloroethane? Which of them will have zero dipole movement?

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273.

Arrange the following alkyl halides in the decreasing order of SN2 reactivity.



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274.

Give reasons:
Iodoform is obtained by the reaction of acetone with hypoidodide ion and not with iodide ion.

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275. Give reasons:

Dry gaseous hydraulic acid and not their aqueous solutions are used to prepare alkyl halides from alkenes.
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276.

How will you prepare 1, 2-ethane diol from 1-chloro ethane?

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277.

How will you prepare 1-bromo propane from 2-bromo propane?

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278.

How will you prepare 1-bromo propane from 1-chloro propane?

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279. Start from chlorobenzene how will you obtain Toluene.

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280. Start from chlorobenzene how will you obtain Phenol.

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