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 Multiple Choice QuestionsShort Answer Type

371.

What happens when trimethylene dibromide is heated with zinc?

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372. Why alkyl halide has the highest density then water and why?
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373.

How will you obtain 2-bromopropane from propene?

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374. Account for the following observation:
The boiling point of ethyl bromide is higher than that of ethyl chloride.
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375.

Account for the following observation:
n-propyl chloride boils at a high temperature than methyl chloride.

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376.

Account for the following observation:
Haloalkanes are denser than the corresponding hydrocarbons.

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377. Explain the following terms:
(i) Nucleophile (ii) Nucleophilic reagent and (iii) Nucleophilic substitution.


i) A nucleophile is a chemical species that donates an electron pair to an electrophile to form a chemical bond in realtion to a reaction.

ii) a nucleophilic reagent defined as the molecules or ions with a free pair of electrons or at least one pi bind can act as nucleophiles. For example OH- Cl-, CN- etc

iii) Nucleophilic substitution reaction:- A nucleophile react with haloalkane having a partial positive on the carbon atom bonded to halogen. a substitution reaction take place and atom attached to the substrate departs as leaving atom or ion. Since the substitution reaction is initiated by a nucleophile it is called substitution reaction.For example nucleophillic substitution reaction of alkyl halides.



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378. How will you distinguish between Vinyl chloride and ethyl chloride.
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379. How will you distinguish between Chlorobenzene and cyclohexyl chloride.
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380. How will you distinguish between Ethyl chloride and ethyl bromide.
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