Give reasons:
The presence of nitro group (–NO2) at o/p positions increases the reactivity of haloarenes towards nucleophilic substitution reactions.
The presence of nitro groups (–NO2) at o/p positions increases the reactivity of haloarenes towards nucleophilic substitution reactions because nitro groups (–NO2) at o/p positions withdraw the electron density from the benzene ring facilitating the attack of the nucleophile. The negative charge in the carbanion formed, at ortho and para positions with respect to a halogen atom, is stabilised through resonance and the presence of nitro groups (–NO2), respectively.
Which alkyl halide from the following pair is chiral and undergoes faster SN2 reaction?
Out of SN1 and SN2, which reaction occurs with
(a) Inversion of configuration
(b) Racemisation
Draw the structure of major monohalo product in each of the following reactions:
i)
ii)