Which of the following compound will give positive iodoform test?

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 Multiple Choice QuestionsMultiple Choice Questions

531.

The rate of SN2 reaction is maximum when the solvent is

  • CH3OH

  • H2O

  • DMSO

  • Benzene


532.

The IUPAC name of the compound  is 

  • 1-bromo-1-chloro-4, 4'-bicyclobutane

  • 4-( 4'-chlorocyclobutyl)-1-bromocyclobutane

  • 3-bromo-3'-chloro-1, 1-bicyclobutane

  • 4-(4'-bromocyclobutyl)-1-chlorocyclo butane


533.

Which of the following compound is used as a refrigerant?

  • CCl4

  • CCl2F2

  • CF4

  • Acetone


534.

What is the chemical composition of Nicol prism?

  • Al2O3

  • CaSO4

  • CaCO3

  • Na3AlF6


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535.

Which of the following compound will give positive iodoform test?

  • Isopropyl alcohol

  • Propionaldehyde

  • Ethylphenyl ketone

  • Benzyl alcohol


A.

Isopropyl alcohol

Alcohols (and aldehydes and Ketones) on heating with X2 (Cl2, Br2, l2) and OH form CHX3 (haloform). This reaction is given by the following molecules-

(i) CH3CH2OH

(ii) CH3-C|OHHR (2° alcohol with -OH at C2)

(iii) CH3C|OHR (Keto group at C2 or compound with acetyl CH3CO group)

(iv) CH3CHO

Therefore, isopropyl alcohol will give positive iodoform test.


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536.

The conversion of ethyl bromide using sodium iodide and dry acetone, this reaction is known as

  • Swarts reaction

  • Finkelstein reaction

  • Sandmeyer reaction

  • Stephen reaction


537.

X and Y in the below reaction are .... and .... respectively

C6H5 - CO2H + X heat C6H5 - COCl QuinolineH2, Pd / BaSO4

  • SOCl2 and C6H5CHO

  • (COCl)2 and C6H5CH3

  • SOCl2 and C6H5CH3

  • (COCl)2 and C6H5CH2OH


538.

The major product P formed in the following reaction is


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539.

The correct order of increasing reactivity of the following alkyl halides, CH3CH2CH(Br)CH3

(I) CH3CH2CH(Br)CH3

(II) (CH3)2CClCH2CH3

(III) CH3CH2CH2Cl and

(IV) Towards SN2 displacement is

  • I < II < III < IV

  • III < I < IV < II

  • III < I < II < IV

  • II < IV < I < III


540.

The product Y for the below reaction is


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