In which of the following compounds, the chlorine atom is most ea

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 Multiple Choice QuestionsMultiple Choice Questions

581.

Which one of the following notations shows product incorrectly?

  • Cm96242 (α, 2n) Bk97243

  • B510 (α, n) N713

  • N714 (n, p) C614

  • Si1428 (d, n) P1529


582.

Carbon-halogen bond is strongest among the following

  • CH3Cl

  • CH3Br

  • CH3F

  • CH3I


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583.

In which of the following compounds, the chlorine atom is most easily substituted?

  • Chlorobenzene 

  • Vinyl chloride

  • Allyl chloride

  • p-chlorotoluene


C.

Allyl chloride

The chlorine atom is most easily substituted from allyl chloride because after the removal of chloride ion most stable allyl carbocation is obtained.

CH2=CH-CH2Cl -Cl- CH2=CH-C+H2(Moststable)

While in vinyl chloride and chloro benzene both C-Cl bond have partial double bond character due to resonance, hence they are more stable and does not undergo nucleophilic substitution reaction.


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584.

Most stable ion is

  • C6H5CH2+

  • (CH3)3-C+

  • (CH3)2CH+

  • CH3CH2+


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585.

Formation of 2-butene as major product by dehydration of 2-butanol is according to

  • Markownikoff rule

  • Saytzeff rule

  • Peroxide effect

  • Anti-Markownikoff rule


586.

Ethane is formed by the reaction of methyl iodide and sodium metal in dry ether solution. This reaction is known as

  • Clemmensen's reduction

  • Kolbe's reaction

  • Wurtz reaction

  • Cannizaro's reaction


587.

Which of the following does not contain chiral carbon atom?

  • Lactic acid

  • 2-chlorobutanoic acid

  • Tartaric acid

  • Succinic acid


588.

Base catalysed aldol condensation occurs with

  • benzaldehyde

  • 2-methyl propionaldehyde

  • 2, 2-dimethyl propionaldehyde

  • None of the above


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589.

Product C is


590.

The boiling points of three isomeric pentanes 1, 2 and 3 are

(1) 9.5°C
(2) 28°C
(3) 36°C
1, 2 and 3 are respectively

  • n-pentane, iso-pentane, neo-pentane

  • iso-pentane, neo-pentane, n-pentane

  • n-pentane, neo-pentane, iso-pentane

  • neo-pentane, iso-pentane, n-pentane


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