Which among the following is a catalyst for the preparation of Grignard reagent ?
Iron powder
Iodine powder
Activated charcoal
Manganese dioxide
Which is not present in Grignard reagent ?
Methyl group
Magnesium ion
Halogen atom
Carboxylic group
Which ligand is useful for removal of the toxic effect of lead metal in body in chelate therapy treatment?
AsO
CH3COO-
(COO-)2
Chlorobenzene is o, p-directing in electrophilic substitution reaction. The directing influence is explained by
+M of Ph
+I of Cl
+M of Cl
-I of Ph
Out of
Relative stabilities order is
4 < 2 < 3 < 1
2 > 4 < 3 < 1
4 < 2 < 1 < 3
2 < 4 < 1 < 3
A.
4 < 2 < 3 < 1
Due to the presence of phenyl group the stabihties of the carbocations 1, 2 and 3 are greater than cation 4, (due to resonance). Further the presence of electron-donating groups on phenyl ring increases the stability of carbocation.
Hence, cation 1 and 3 are more stable than cation 2. Moreover - OMe group shows +M effect which is more prominent than +I effect of -Me group. Thus, cation 1 is more stable than cation 3. So, the correct order is, 4 < 2 < 3 < 1.
CH3MgBr + CH2 = CH-COH Product
It is (1 : 4 addition)
CH2=CH-
CH2OH-CH=CH-CH3
CH3CH2CH2CHO
None of the above
Which one is least reactive in a nucleophilic substitution reaction?
CH3CH2Cl
CH2=CHCH2Cl
CH2=CHCl
(CH3)3CCl