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 Multiple Choice QuestionsMultiple Choice Questions

621.

Which among the following is a catalyst for the preparation of Grignard reagent ?

  • Iron powder

  • Iodine powder

  • Activated charcoal

  • Manganese dioxide


622.

The chirality of the compound

  • R

  • S

  • Z

  • E


623.

Which is not present in Grignard reagent ?

  • Methyl group

  • Magnesium ion

  • Halogen atom

  • Carboxylic group


624.

Which ligand is useful for removal of the toxic effect of lead metal in body in chelate therapy treatment?

  • AsO43-

  • CH3COO-

  • (COO-)2


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625.

Chlorobenzene is o, p-directing in electrophilic substitution reaction. The directing influence is explained by

  • +M of Ph

  • +I of Cl

  • +of Cl

  • -I of Ph


626.

The end product 'C' in the following reaction-


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627.

Out of

Relative stabilities order is

  • 4 < 2 < 3 < 1

  • 2 > 4 < 3 < 1

  • 4 < 2 < 1 < 3

  • 2 < 4 < 1 < 3


A.

4 < 2 < 3 < 1

Due to the presence of phenyl group the stabihties of the carbocations 1, 2 and 3 are greater than cation 4, (due to resonance). Further the presence of electron-donating groups on phenyl ring increases the stability of carbocation.

Hence, cation 1 and 3 are more stable than cation 2. Moreover - OMe group shows +M effect which is more prominent than +I effect of -Me group. Thus, cation 1 is more stable than cation 3. So, the correct order is, 4 < 2 < 3 < 1.


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628.

CH3MgBr + CH2 = CH-COH H3O+ Product

It is (1 : 4 addition)

  • CH2=CH-C||CH3OH-H

  • CH2OH-CH=CH-CH3

  • CH3CH2CH2CHO

  • None of the above


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629.

Which one is least reactive in a nucleophilic substitution reaction?

  • CH3CH2Cl

  • CH2=CHCH2Cl

  • CH2=CHCl

  • (CH3)3CCl


630.

The number of moles of Grignard reagent consumed per mole of the compound

  • 2

  • 3

  • 1

  • 4


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