Why carbon-carbon distance in benzene is intermediate between ca

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 Multiple Choice QuestionsShort Answer Type

201.

You are given samples of ethane, ethene and ethyne in three different containers. How will you distinguish them?

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 Multiple Choice QuestionsLong Answer Type

202.

What are aromatic hydrocarbons or arenes?

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203.

Explain isomerism in arenes.

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204.

Discuss the structure of benzene with special reference to Kekule structure. 

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205. Discuss the molecular orbital structure of benzene (Delocalisation of straight pi-electrons).
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 Multiple Choice QuestionsShort Answer Type

206.

What do you mean by delocalisation of straight pi-electrons?

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207.

Benzene ring has three double bonds in it but is still quite stable. Explain.

Or

Why is benzene extra-ordinary stable though it contains three double bonds?

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208. Why carbon-carbon distance in benzene is intermediate between carbon-carbon single and double bond?


Each carbon atom of benzene is sphybridised. The unhybridised p-orbital of each carbon atom overlaps to a small but equal extent with the unhybridised p-orbitals of both the adjacent carbon atoms. This leads to the formation of molecular orbital embracing all the six carbon atoms. Due to the delocalisation of –electron clouds above and below the plane of the benzene ring, all the carbon-carbon bonds acquire slight double bond character. Thus carbon-carbon bond length in benzene lies in between C–C and C=C bond length.
Standard C–C bond length = 154 pm
Standard C=C bond length = 134 pm
But C–C bond length in benzene = 139 pm.

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 Multiple Choice QuestionsLong Answer Type

209. What is resonance? Discuss the resonance in benzene. What is the effect of resonance ?
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 Multiple Choice QuestionsShort Answer Type

210.

What is resonance energy?

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