Why does benzene undergo electrophilic substitution reactions ea

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 Multiple Choice QuestionsShort Answer Type

231. What happens when:
Toluene is heated with concentrated sulphuric acid.
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232. What happens when:
p-xylene is heated with alkaline KMnO4.
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233.

What happens when:
Benzene is treated with n-propyl chloride in the presence of anhydrous AlCl3.

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 Multiple Choice QuestionsLong Answer Type

234.

Discuss the mechanism of electrophilic substitution reactions of benzene?

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235. Discuss the mechanism of chlorination of benzene.
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236.

How is benzene converted to nitrobenzene? Give mechanism.

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237.

How benzene is converted into benzene sulphonic acid? Give its mechanism.
Or
Explain the mechanism of sulphonation of benzene.

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238.

Discuss the mechanism of Friedel Craft’s reaction.
Or
Discuss the mechanism of Friedel Craft’s alkylation of benzene. Give the mechanism of reaction of benzene within  the presence of AlCl3.

Or

How is benzene converted into aceto-phenone? Name the reaction and discuss the mechanism explaining each step.

Or

Give the mechanism of acylation of benzene.

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 Multiple Choice QuestionsShort Answer Type

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239.

Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?


Benzene is a rich source of an electron because of the presence of electron cloud containing -electrons above and below the plane of the ring. As a result, it attracts the electrophiles (electron-deficient species) towards it and repels nucleophiles (electron-rich species). Hence benzene undergoes electrophilic substitution reactions easily.

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 Multiple Choice QuestionsLong Answer Type

240.

Discuss the directive influence of substituents on disubstitution in benzene. 

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