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 Multiple Choice QuestionsMultiple Choice Questions

311.

Which of the following on combustion gives maximum energy?

  • Ethane

  • Propane

  • Methane 

  • Butane


312.

C2H6 + CH3Cl Anhy. AlCl3 C6H5CH3 + HCl

The name of the above reaction is

  • Gattermann

  • Reimer-Tiemann

  • Friedel-Craft

  • Cannizzaro


313.

The tetraethyl lead mixed in petrol works as 

  • cooling agent

  • anti-knocking agent

  • bleaching agent

  • None of the above


314.

The number of alkenyl groups possible from C4H7 are

  • 7

  • 5

  • 3

  • 8


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315.

Among the following select the alkane that is expected to have lowest boiling point

  • hexane

  • 2-methylpentane

  • 3-methylpentane

  • 2,2-dimethylbutane


D.

2,2-dimethylbutane

As the number of carbon atom increases, the boiling points of alkane increases because van der waal's forces increases. However, branching results in decrease in boiling point due to decreased surface area which results in weaker van der waals' forces. Thus, order of boiling points of given alkanes is


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316.

'X' is an optically active alkane having lowest molecular mass, Predict the structure of the major product obtained on monochlorination of 'X'.


317.

Given: R = 8.314 JK-1 mol-1, the work done during combustion of 0.090 kg of ethane (molar mass = 30) at 300 K is

  • -18.7 kJ

  • 18.7 kJ

  • 6.234 kJ

  • -6.234 kJ


318.

What is the possible number of monohydroxy derivatives of a hydrocarbon consisting of five carbon atoms with one methyl group as a branch?

  • 2

  • 3

  • 4

  • 5


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319.

Chlorination of ethane is carried out in the presence of

  • anhydrous AlBr3

  • mercuric chloride

  • ultraviolet light

  • zinc chloride


320.

The compound which is not formed when a mixture of n-butyl bromide and ethyl bromide treated with sodium metal in the presence of dry ether is

  • butane

  • octane

  • hexane

  • ethane


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