An aromatic hydrocarbon with empirical formula C5H4 on treatment

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 Multiple Choice QuestionsMultiple Choice Questions

331.

Two organic compounds X and Y on analysis gave the same percentage composition namely; C = (12/13) × 100% and H = (1/13) × 100%. However, compound X decolourises bromine water while compound Y does not. The two compounds X and Y may be respectively 

  • acetylene and ethylene

  • acetylene and benzene

  • ethylene and benzene

  • toluene and benzene


332.

For preparing an alkane, a saturated solution of sodium or potassium salt of a carboxylic acid is subjected to

  • hydrolysis

  • electrolysis

  • oxidation

  • hydrogenation


333.

The reaction of  with HBr gives predominantly


334.

An organic compound with molecular formula C6H12 upon ozonolysis give only acetone as the product. The compound is

  • 2,3-dimethyl-1-butene

  • 3-hexane

  • 2-hexene

  • 2,3-dimethyl-2-butene


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335.

Which one of the following carbanions is the least stable?

  • CH3CH2-

  • CH3-

  • (CH3)3C-

  • HC≡C-


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336.

An aromatic hydrocarbon with empirical formula C5H4 on treatment with concentrated H2SO4 gave a monosulphonic acid. 0.104 g of the acid required 10 mL of N20 NaOH for complete neutralisation. The molecular formula of hydrocarbon is 

  • C5H4

  • C10H8

  • C15H12

  • C20H16


C.

C15H12

Empirical formula (C5H4) + H2SO4 → Monosulphonic acid

0.104 gm of acid required 10 mL of N20 NaOH for completely neutralisation

0.104n (5 × 12 + 4 × 1) = 120 × 10 × 10-3

n = 10432 = 3.25  ≈ 3

The molecular formula of hydrocarbon will be C15H12.


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337.

An alkene having the molecular formula C9H18 on ozonolysis gives 2, 2-dimethyl propanal and 2-butanone. The alkene is :

  • 2, 2, 2-trimethyl-3-hexene

  • 2, 2, 6-trimethyl-3-hexane

  • 2, 3, 4-trimethyl-2-hexene

  • 2, 2, 4-trimethyl-3-hexene


338.

Observe the following reactions and predict the nature of A and B:

  • A and B both are 

  • A and B both are 

  • A is  and B is 

  • A is  and B is 


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339.

Nitration of aniline in strongly acidic medium, result in the formation of m-nitroaniline also. This is because :

  • amino group is meta orienting during electrophilic substitution reaction

  • nitro group goes always to the meta position irrespective of the substituents

  • nitration of aniline is a nucleophilic substitution reaction in strongly acidic medium

  • in strongly acidic conditions aniline is present as anilinium ion


340.

How many σ and Π bonds are present in toluene?

  • 3Π + 8σ

  • 3Π + 10σ

  • 3Π + 15σ

  • 6Π + 3σ


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