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 Multiple Choice QuestionsMultiple Choice Questions

391.

In chlorination benzene, the reactive species is

  • Cl+

  • Cl-

  • Cl2

  • Cl2-


392.

The number of moles of proton which can be easily given by butyne-1 (1 mole) is

  • 1

  • 2

  • 3

  • 6


393.

The addition of HBr is easiest with

  • CH2=CHCl

  • ClCH=CHCl

  • CH3-CH=CH2

  • (CH3)2C=CH2


394.

The reaction

CH2 = CH2 + H2 250 - 300°CNi CH3-CH3 is called

  • Wurtz reaction

  • Kolbe's reaction

  • Sabatier-Senderens reaction

  • Carbylamine reaction


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395.

Formation of 2-butene as major product by dehydation of 2-butanol is according to

  • Markownikoff's rule

  • Saytzeff's rule

  • Peroxide effect

  • Anti-Markownikoffs rule


396.

Acetic acid dissolved in benzene shows molecular weight

  • 60

  • 120

  • 180

  • 240


397.

Ethene gives with acidic KMnO4 solution

  • ethylene glycol

  • ethylene oxide

  • formaldehyde

  • acetaldehyde


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398.

The strongest ortho/para directing group is

  • -NH2

  • -CH3

  • -Cl

  • -C2H5


A.

-NH2

All those groups which contain at least one pair of non-bonding electrons on the atom adjacent to the benzene ring, are ortho and para directing. Among the given options, all are ortho and para directing but their capacity of ortho-para direction on follows the order.

-N..H2 > -CH3 > -C2H5 >-Cl

Hence, -N..H2 is the strognest ortho-para direction group.


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399.

An organic alkadiene on reductive ozonolysis produces
(i) acetaldehyde
(ii) acetone
(iii) 2-methylpropane-1,3-dial
The formula of alkadiene will be

  • CH3C(CH3)=CHCH(CH3)CH=CHCH3

  • CH3CH(CH3)CH=C(CH3)CH=CHCH3

  • CH3C(CH3)=CHCHC(CH3)=CHCH3

  • CH3CH2CH(CH3)CH=CHC(CH3)=CH2


400.

2-chloro-3-methylbutane is treated with sodium in etherial solution, then it will give

  • 2,4-dimethylhexane

  • 3,5-dimethylhexane

  • 2,3,4,5-tetramethylhexane

  • 2,6-dimethyloctane


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