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 Multiple Choice QuestionsMultiple Choice Questions

531.

What is the product P ?

  • Both (a) and (b)


532.

In the eclipsed conformation of ethane, the dihedral angle between the hydrogen atoms of adjacent methyl groups is :

  • 60°

  • 120°

  • 180°


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533.

The major product of the addition of water molecule to propyne in the presence of mercuric sulphate and dilute sulphuric acid is :

  • ethanal

  • 2-propanol

  • propane

  • propanone


D.

propanone

In the presence of H2SO4 and HgSO4 as a catalyst, H2O adds to triple bond of propyne to form an unstable enol which readily tautomerises to the propanone. Addition occurs according to Markownikoff 's rule.


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534.

Which of the following statements is not an essential feature of an optically active molecule ?

  • It will rotate the plane of polarised light

  • It will have a non-superimposable mirror image

  • It will have no element of symmetry

  • It will have an asymmetric carbon atom


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535.

The reagent which could distinguish between 1-hexyne and 1-hexene is :

  • Ag(NH3)2+

  • KMnO4

  • Br2 in CCl4

  • H2SO4


536.

Choose the correct reagent required to carry out the transformation :

  • Zn + conc. HCl

  • conc. H2SO4

  • Li then H2O

  • H2/Pt


537.

The heat liberated when 1.89 g of benzoic acid is burnt in a bomb calorimeter at 25°C and it increases the temperature of 18.94 kg of water by 0.632°C. If the specific heat of water at 25°C is 0.998 cal/g-deg, the value of the heat of combustion of benzoic acid is

  • 881.1 kcal

  • 771.2 kcal

  • 981.1 kcal

  • 871.2 kcal


538.

Which of the following alkenes will give same product by any method out of hydration, hydroboration-oxidation and oxymercuration-demercuration? 

  • CH3CH=CH2

  • CH3CH=CHCH3

  • CH3CH(CH3)CH=CH2


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539.

The compound formed by the ozonolysis of acetylene :

  • glycol

  • acetic acid

  • ethylene ozonide

  • glyoxal


540.

The compound which have conjugate double bond :

  • butyne

  • butylene

  • isobutylene

  • butadiene


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