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 Multiple Choice QuestionsMultiple Choice Questions

621.

Catalyst used in dimerisation of acetylene to prepare chloroprene is

  • HgSO4 + H2SO4

  • Cu2Cl2

  • Cu2Cl2 + NH4Cl

  • Cu2Cl2 + NH4OH


622.

The dehydration of butan-1-ol gives

  • 1-butene as the main product

  • 2-butene as the main product

  • equal amounts of 1-butene and 2-butene

  • 2-methyl propene


623.

Cetane is a compound which has very good ignition property. Chemically it is

  • CH3(CH2)14CH3

  • (CH3)3C(CH2)11CH3

  • C17H34

  • None of the above


624.

The electrophile involved in the nitration of benzene is :

  • NO2

  • NO2+

  • NO

  • NO2-


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625.

Which of the following is most reactive towards electrophilic nitration ?

  • Toluene

  • Benzene

  • Benzoic acid

  • Nitrobenzene


626.

The most suitable reagent for the following conversion, is :

   

  • H2, Pd/C, quinoline

  • Zn/HCl

  • Hg2+/H+, H2O

  • Na/liquid NH3


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627.

The number of sigma (σ) and pi (π) pent-2-en-4-yne is

  • 8σ bonds and 5π bonds

  • 11σ bonds and 2π bonds

  • 13σ bonds and no π bonds

  • 10σ bonds and 3π bonds


D.

10σ bonds and 3π bonds

Number of σ bonds = 10 and number of π bonds = 3.


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628.

Among the following, the reaction that proceeds through an electrophilic substitution, is:


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629.

An alkene "A" on reaction with O3 and Zn–H2O gives propanone and ethanal in equimolar ratio. Addition of HCl to alkene "A" gives "B" as the major product. The structure of product "B" is:

  • H3C—CH2—CH(CH2Cl)—CH3


630.

Provide an acceptable name for the alkene shown below:

  • 5-ethyl-6-methyl-propyl decane

  • 2-ethyl-6-methyl-2-propyldecane

  • 2-ethyl-6-methyl-5-propyldecane

  • 6-ethyl-2-methyl-5-propyldecane


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