What characteristics do you expect from an electron-deficient h

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 Multiple Choice QuestionsLong Answer Type

91.

Distinguish clearly between salt like hydrides and covalent hydrides.

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92.

What do you understand by:
(i) electron deficient
(ii) electron-precise and
(iii) electron rich compounds of hydrogen?
Provide justification with suitable examples.

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 Multiple Choice QuestionsShort Answer Type

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93.

What characteristics do you expect from an electron-deficient hydride with respect to its structure and chemical reactivity ? 


Since electron deficient hydrides have lesser electrons to form normal covalent bonds, therefore we expect the following characteristics from these hydrides:

(i) They generally exist in polymeric forms such as B2H6, B4H10.(AlH3)n etc.

(ii) They react with many metals, non-metals and their compounds. Hence these hydrides are very reactive. 

          

(iii) They act as Lewis acids and thus form complexes with Lewis bases.


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94.

Do you expect the carbon hydride of the type(CnH2n+2) to act as Lewis acid or base? 

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 Multiple Choice QuestionsLong Answer Type

95.

What do you understand by the term ‘non-stoichiometic hydrides’? Do you expect this type of hydrides to be formed by alkali metals?

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 Multiple Choice QuestionsShort Answer Type

96.

Saline hydrides are known to react with water violently producing fire. Can CO2, a well-known fire extinguisher, be used in this case? Explain.

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97.

What do you expect the nature of hydrides if formed by elements of atomic numbers 15, 19, 23, 44 with dry dihydrogen? Compare their behaviour towards water. 

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98.

How saline hydrides can remove traces of water from organic compounds?

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99.

Can Phosphorus with outer electronic configuration 3s23p3 form PH5?
Or

P forms PH3 but not PH5. Comment.

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100. Arrange the following:
CaH2, BeH2 and TiH2 in order of increasing electric conductance.
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