What do you mean by redox reactions in aqueous solutions? Give e

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 Multiple Choice QuestionsLong Answer Type

61.

Show that oxidation cannot occur without reduction.
Or
Show that oxidation and reduction go side by side.

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62. In the following reactions:
space space left parenthesis straight i right parenthesis space straight H subscript 2 straight O space plus space 2 FeCl subscript 3 space space space space space rightwards arrow space space space space 2 FeCl subscript 2 space plus space 2 HCl space plus space straight S
space space left parenthesis ii right parenthesis space 2 Al space plus space Fe subscript 2 straight O subscript 3 space space rightwards arrow space space space Al subscript 2 straight O subscript 3 space plus space 2 Fe

which is oxidised to what and which is reduced to what? Also, mention the oxidising and reducing agent.
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 Multiple Choice QuestionsShort Answer Type

63.

Identify the oxidant and the reductant in the following reactions:
left parenthesis straight i right parenthesis space Zn left parenthesis straight s right parenthesis space plus space 1 half straight O subscript 2 left parenthesis straight g right parenthesis space space rightwards arrow space space ZnO left parenthesis straight s right parenthesis
left parenthesis ii right parenthesis space Zn left parenthesis straight s right parenthesis space plus space 2 straight H to the power of plus left parenthesis aq right parenthesis space space rightwards arrow space space Zn to the power of 2 plus end exponent left parenthesis aq right parenthesis space plus space straight H subscript 2 left parenthesis straight g right parenthesis

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64. In the reactions given below, identify the species undergoing oxidation and reduction:

left parenthesis straight i right parenthesis space straight H subscript 2 straight S left parenthesis straight g right parenthesis space plus space Cl subscript 2 left parenthesis straight g right parenthesis space space rightwards arrow space space space 2 HCl space left parenthesis straight g right parenthesis space plus space space straight S left parenthesis straight s right parenthesis
left parenthesis ii right parenthesis space 3 Fe subscript 3 straight O subscript 4 left parenthesis straight s right parenthesis space plus space 8 Al space left parenthesis straight s right parenthesis space rightwards arrow space space space 9 space Fe left parenthesis straight s right parenthesis space plus space 4 Al subscript 2 straight O subscript 3 left parenthesis straight s right parenthesis
left parenthesis iii right parenthesis space 2 Na left parenthesis straight s right parenthesis space plus space straight H subscript 2 left parenthesis straight g right parenthesis space rightwards arrow space space 2 NaH left parenthesis straight s right parenthesis
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65. Using Stock notation, represent the following compounds : HAuCl4, Tl2O,FeO, Fe2O3, CuI, CuO, MnO and MnO2?
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66.

How will you classify the redox reactions?

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 Multiple Choice QuestionsLong Answer Type

67.

What are the changes which take place when a redox reaction is carried in a beaker? Explain with the help of a suitable example.
Or
Explain the redox reaction

Zn space plus space CuSO subscript 4 space space rightwards arrow space space ZnSO subscript 4 space plus space Cu
occurring in a beaker.



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68.

What do you mean by redox reactions in aqueous solutions? Give examples.


A large number of redox reactions proceed slowly in aqueous solutions. Each redox reaction can be considered as a sum of two half reactions-one involving oxidation called oxidation half reaction and the other involving reduction called reduction half reaction. For example;

(a) Let us consider the oxidation of aqueous potassium iodide by hydrogen peroxide. This reaction can be divided into two half reactions.


Supplying the required number of spectator ions, the balanced redox equation is

        
Note. The ions which do not part in any reaction but are simply added to balance the charge are called spectator ions.

(b) Consider the oxidation of aqueous ferrous sulphate to ferric sulphate by aqueous acidified KMnO4 solution.




Supplying the required spectator ions, the complete balanced redox equation is

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 Multiple Choice QuestionsShort Answer Type

69.

Write the half reactions for each of the following redox reactions:
left parenthesis straight a right parenthesis space 2 Fe to the power of 3 plus end exponent left parenthesis aq right parenthesis space plus space 2 straight I to the power of minus left parenthesis aq right parenthesis space space rightwards arrow space space straight I subscript 2 left parenthesis straight s right parenthesis space plus space 2 Fe to the power of 2 plus end exponent left parenthesis aq right parenthesis
left parenthesis straight b right parenthesis space Sn to the power of 2 plus end exponent left parenthesis aq right parenthesis space plus space 2 Hg to the power of 2 plus end exponent left parenthesis aq right parenthesis space rightwards arrow space space Sn to the power of 4 plus end exponent left parenthesis aq right parenthesis space plus space 2 straight H to the power of plus left parenthesis aq right parenthesis

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 Multiple Choice QuestionsLong Answer Type

70. In the following reactions:

1. space 2 Na left parenthesis straight s right parenthesis space plus space Cl subscript 2 left parenthesis straight g right parenthesis space space space rightwards arrow space space space 2 NaCl left parenthesis straight s right parenthesis
2. space Mg left parenthesis straight s right parenthesis space plus space Cl subscript 2 left parenthesis straight g right parenthesis space space rightwards arrow space space MgCl subscript 2 left parenthesis straight s right parenthesis
3. space Zn left parenthesis straight s right parenthesis space plus space 2 straight H to the power of plus left parenthesis aq right parenthesis space space rightwards arrow space space Zn to the power of 2 plus end exponent left parenthesis aq right parenthesis space plus space straight H subscript 2 left parenthesis straight g right parenthesis
Mention:
(i) Which reactant is oxidised? To what?
(ii) Which reactant is an oxidising agent?
(iii) Which reactant is reduced?
(iv) Which reactant is reducing agent?

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