Which of the following species, do not show disproportionation r

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 Multiple Choice QuestionsShort Answer Type

81.

Consider the reactions:
(a) H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)

(b) H3PO2(aq) + 2CuSO4(aq) + 2H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)

(c) C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH(aq) → C6H5COO(aq)+ 2Ag(s) +4NH3 (aq) + 2H2O(l)

(d) C6H5CHO(l) + 2Cu2+(aq) + 5OH(aq) → No change observed.

What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions ?

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 Multiple Choice QuestionsLong Answer Type

82. Determine the oxidation number of: (i) Si in SiH4 (ii) B in BH(iii) B in BF3
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83. Give the points of difference between valency and oxidation number?
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84.

Discuss briefly the types of redox reactions. Give examples. 
or
Discuss the following redox reactions.
(a) Combination reactions
(b) Decomposition reactions
(c) Displacement reactions
(d) Disproportionation reactions.
Give one example in each case.

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85.

Suggest a scheme of classification of the following redox reactions:
(a) N2(g) + O2(g) → 2 NO (g)
(b) 2Pb(NO3)2(s) → 2PbO(s) + 2 NO2 (g) + ½ O2 (g)
(c) NaH(s) + H2O(l) → NaOH(aq) + H2 (g)
(d)2NO2(g) + 2OH(aq) → NO2-(aq) +NO3(aq)+H2O(l)



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 Multiple Choice QuestionsShort Answer Type

86.

Refer to the periodic table given in your book and now answer the following questions:
(a) Select the possible non-metals that can show disproportionation reaction.
(b) Select three metals that can show disproportionation reaction.

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 Multiple Choice QuestionsLong Answer Type

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87. Which of the following species, do not show disproportionation reaction and why?
ClO, ClO2, ClO3- and ClO4– 
Also write reaction for each of the species that disproportionates.


ClO(hydrochlorite ion):


ClO4-1 (perchlorate ion) cannot show any disproportionation reaction. The oxidation state of Cl is ClO4- ion is +7. It is the maximum oxidation state which it can have. It is the maximum oxidation state which it can have. It can decrease the same by undergoing reduction and not increase it anymore hence ClO4- ion does not undergo disproportionation reactions.




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 Multiple Choice QuestionsShort Answer Type

88.

What sorts of informations can you draw from the following reaction?
(CN)2(g) + 2OH (aq) → CN(aq) + CNO(aq) + H2O(l)

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89.

Suggest a scheme of classification of the given redox reactions,

 N2 (g) + O2 (g) rightwards arrow 2NO (g)

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90. What sorts of information can you draw from the following reaction?
(CN)2(g) + 2OH(aq) → CN(aq) + CNO(aq) + H2O(l)
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